20160
正丁基锂 溶液
~1.6 M in hexanes
别名:
1-丁基锂, n-BuLi, Butyl lithium, 丁基锂 溶液
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关于此项目
线性分子式:
CH3(CH2)3Li
化学文摘社编号:
分子量:
64.06
PubChem Substance ID:
UNSPSC Code:
12352103
Beilstein/REAXYS Number:
1209227
MDL number:
form
liquid
shelf life
limited shelf life
concentration
~1.6 M in hexanes
color
yellow
density
0.68 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]CCCC
InChI
1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
InChI key
MZRVEZGGRBJDDB-UHFFFAOYSA-N
Other Notes
This product has been replaced by 186171-ALDRICH | n-Butyllithium solution 1.6 M in hexanes
Disclaimer
长时间储存可形成氢化锂沉淀
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signalword
Danger
target_organs
Central nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
10.4 °F - closed cup
flash_point_c
-12 °C - closed cup
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
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Bernhard J Ueberbacher et al.
Chemical communications (Cambridge, England), (28)(28), 3287-3289 (2008-07-16)
An ortho-metalation method for free ferrocenyl alcohols has been developed, which allows preparation of planar chiral ferrocene derivatives with high yields and diastereoselectivities.
Petra Rönnholm et al.
Organic letters, 9(19), 3781-3783 (2007-08-19)
A robust and scaleable route to chiral 1-isopropylamino-2-(diphenylphosphino)ethanes is described via the ring-opening of chiral, cyclic sulfamidates with potassium diphenylphosphide (KPPh(2)). The novel protocol offers a robust access to gram quantities of chiral amino phosphinoethanes in high yields. The Li-amides
Enantioselective total synthesis of the marine toxin (-)-gymnodimine employing a Barbier-type macrocyclization.
Ke Kong et al.
Angewandte Chemie (International ed. in English), 48(40), 7402-7405 (2009-09-04)