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Merck
CN

23185

氯甲酸-9-芴基甲酯

purum, ≥98.0% (HPLC)

别名:

9-芴甲氧羰酰氯, Fmoc-Cl, 芴甲氧羰酰氯

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关于此项目

经验公式(希尔记法):
C15H11ClO2
化学文摘社编号:
分子量:
258.70
EC Number:
249-313-6
UNSPSC Code:
12352005
PubChem Substance ID:
Beilstein/REAXYS Number:
2279177
MDL number:
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InChI key

IRXSLJNXXZKURP-UHFFFAOYSA-N

InChI

1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2

SMILES string

ClC(=O)OCC1c2ccccc2-c3ccccc13

grade

purum

assay

≥98.0% (HPLC)

mp

61-63 °C, 62-64 °C (lit.)

application(s)

peptide synthesis

functional group

Fmoc

storage temp.

2-8°C

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Application

在氨基酸 HPLC 分析中,用于衍生化氨基酸;在固相肽合成中用于制备 N-Fmoc 氨基酸。

Other Notes

用于引入氨基保护基团 9-芴甲氧羰基 (Fmoc),Fmoc 对酸和催化氢化反应稳定,但在温和碱性非水解条件下易被裂解;Fmoc 基团可用于保护羟基;保护核苷酸中的氨基

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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分析证书(COA)

Lot/Batch Number

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L.A. Carpino
Accounts of Chemical Research, 20, 401-401 (1987)
Synthesis of phosphate-methylated DNA fragments using 9-fluorenylmethoxycarbonyl as transient base protecting group.
Koole, L.H
The Journal of Organic Chemistry, 54, 1657-1657 (1989)
Khaggeswar Bheemanapally et al.
Scientific reports, 10(1), 7134-7134 (2020-04-30)
Glutamine (Gln) is converted to excitatory (glutamate, aspartate) and inhibitory (γ-amino butyric acid) amino acid neurotransmitters in brain, and is a source of energy during glucose deprivation. Current research utilized an Analytical Quality by Design approach to optimize levels and
C. Gioeli et al.
Journal of the Chemical Society. Chemical Communications, 672-672 (1982)
James Z Fan et al.
Nanoscale, 11(22), 10774-10781 (2019-05-28)
Colloidal quantum dots have garnered significant interest in optoelectronics, particularly in quantum dot solar cells (QDSCs). Here we report QDSCs fabricated using a ligand that is modified, following film formation, such that it becomes an efficient hole transport layer. The

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