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Merck
CN

25204

甲酸铵

purum, ≥98%

别名:

甲酸 铵盐

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关于此项目

线性分子式:
HCO2NH4
化学文摘社编号:
分子量:
63.06
EC Number:
208-753-9
UNSPSC Code:
12352300
PubChem Substance ID:
Beilstein/REAXYS Number:
3625095
MDL number:
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grade

purum

assay

≥98%

impurities

≤0.002% heavy metals (as Pb)

pH

6-7 (20 °C, 5%)

mp

119-121 °C (lit.)

density

1.26 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤100 mg/kg

cation traces

Fe: ≤20 mg/kg

SMILES string

N.OC=O

InChI

1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3

InChI key

VZTDIZULWFCMLS-UHFFFAOYSA-N

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Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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分析证书(COA)

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Debenzylation of N-benzylamino derivatives by catalytic transfer hydrtyation with ammonium formate.
Ram S and Spicer LD.
Synthetic Communications, 17(4), 415-418 (1987)
Lucie Nováková et al.
Analytica chimica acta, 950, 199-210 (2016-12-06)
High throughput general chiral screening method using supercritical fluid chromatography was developed. This method takes an advantage of very fast gradient screening (3 min + 1 min isocratic hold) and generic enantioselectivity of the combined additive formed by 0.1% trifluoroacetic (TFA) acid and 0.1%
Rapid debenzylation of N-benzylamino derivatives to amino-derivatives using ammonium formate as catalytic hydrogen transfer agent.
Ram S and Spicer LD.
Tetrahedron Letters, 28(5), 515-516 (1987)
A convenient method for the N-formylation of secondary amines and anilines using ammonium formate.
Reddy PG, et al.
Tetrahedron Letters, 41(47), 9149-9151 (2000)
The palladium assisted transfer reduction of a, ?-unsaturated nitroalkenes to oximes using ammonium formate.
Kabalka GW, et al.
Synthetic Communications, 20(16), 2453-2458 (1990)

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