等级
ACS reagent
蒸汽压
1.3 mmHg ( 546 °C)
方案
≥90%
≥90.0% CuCl basis (ACS specification)
表单
crystalline powder
powder
反应适用性
reagent type: catalyst
core: copper
杂质
≤0.02% insol. in acid
沸点
1490 °C (lit.)
mp
430 °C (lit.)
溶解性
dimethyl sulfide: partially soluble(lit.)
water: insoluble(lit.)
痕量阴离子
sulfate (SO42-): ≤0.1%
痕量阳离子
Ca: ≤0.01%
Fe: ≤0.005%
K: ≤0.02%
Na: ≤0.05%
SMILES字符串
Cl[Cu]
InChI
1S/ClH.Cu/h1H;/q;+1/p-1
InChI key
OXBLHERUFWYNTN-UHFFFAOYSA-M
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应用
作为自由基反应（如 α,β-不饱和酮的锡氢化作用）的引发剂表现出独特的性质。
Copper(I) chloride may be used in the following processes:
- Along with magnesium chloride, to catalyze the conjugate addition of organomagnesium reagents to α,β-ethylenic ketones to form 1,4-addition products.
- To facilitate the addition of an amine to a nitrile to form an amidine, which on reduction forms tertiary amine.
- To catalyze the reaction of olefinic hydrocarbons with phenyl selenocyanate to form β-alkoxyalkyl phenyl selenide.
其他说明
A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Conversion of nitriles into tertiary amines: N,N-dimethylhomoveratrylamine
Rousselet G, et al
Organic Syntheses, 76, 133-133 (1996)
Facile oxyselenation of olefins in the presence of copper (II) or copper (I) chloride as catalyst.
Toshimitsu A, et al.
The Journal of Organic Chemistry, 45(10), 1953-1958 (1980)
M. Alami et al.
Organic Syntheses, 72, 135-135 (1995)
Copper (I) chloride-mediated intramolecular coupling of vinyltrimethylstannane and vinyl halide functions.
Piers E and Wong T.
The Journal of Organic Chemistry, 58(14), 3609-3610 (1993)
Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
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