氯化亚铜

Name: 氯化亚铜
Brand: SIAL

ACS reagent, ≥90%

别名:

一氯化铜

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关于此项目

线性分子式:

CuCl

化学文摘社编号:

7758-89-6

分子量:

99.00

UNSPSC Code:

12352300

PubChem Substance ID:

24855533

EC Number:

231-842-9

MDL number:

MFCD00010971

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InChI key

OXBLHERUFWYNTN-UHFFFAOYSA-M

InChI

1S/ClH.Cu/h1H;/q;+1/p-1

SMILES string

Cl[Cu]

grade

ACS reagent

vapor pressure

1.3 mmHg ( 546 °C)

assay

≥90%, ≥90.0% CuCl basis (ACS specification)

form

crystalline powder, powder

reaction suitability

reagent type: catalyst
core: copper

impurities

≤0.02% insol. in acid

bp

1490 °C (lit.)

mp

430 °C (lit.)

solubility

dimethyl sulfide: partially soluble(lit.), water: insoluble(lit.)

anion traces

sulfate (SO₄^2-): ≤0.1%

cation traces

Ca: ≤0.01%, Fe: ≤0.005%, K: ≤0.02%, Na: ≤0.05%

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Application

作为自由基反应（如 α,β-不饱和酮的锡氢化作用）的引发剂表现出独特的性质。

Copper(I) chloride may be used in the following processes:

Along with magnesium chloride, to catalyze the conjugate addition of organomagnesium reagents to α,β-ethylenic ketones to form 1,4-addition products.
To facilitate the addition of an amine to a nitrile to form an amidine, which on reduction forms tertiary amine.
To catalyze the reaction of olefinic hydrocarbons with phenyl selenocyanate to form β-alkoxyalkyl phenyl selenide.

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.