等级
technical
方案
~70% (RT)
反应适用性
reagent type: oxidant
杂质
~10% 3-chlorobenzoic acid
~20% water
mp
69-71 °C (lit.)
储存温度
2-8°C
SMILES字符串
OOC(=O)c1cccc(Cl)c1
InChI
1S/C7H5ClO3/c8-6-3-1-2-5(4-6)7(9)11-10/h1-4,10H
InChI key
NHQDETIJWKXCTC-UHFFFAOYSA-N
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其他说明
用于烯烃环氧化的试剂
警示用语:
Danger
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1
储存分类代码
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
G.M. Rubottom et al.
Organic Syntheses, 7, 282-282 (1990)
Evgeny V Kudrik et al.
Nature chemistry, 4(12), 1024-1029 (2012-11-24)
High-valent oxo-metal complexes are involved in key biochemical processes of selective oxidation and removal of xenobiotics. The catalytic properties of cytochrome P-450 and soluble methane monooxygenase enzymes are associated with oxo species on mononuclear iron haem and diiron non-haem platforms
Which oxidant is really responsible for P450 model oxygenation reactions? A kinetic approach.
Alicja Franke et al.
Angewandte Chemie (International ed. in English), 47(28), 5238-5242 (2008-06-04)
Atul P Singh et al.
Chemical communications (Cambridge, England), 48(58), 7298-7300 (2012-06-16)
Bis-arylsulfide BODIPY systems were prepared and studied for multiple O-atom sensing (at 522 nm); 2- and 3-atom loading was optimal (50-fold, "turn on"). Neuronal studies showed greater H(2)O(2) sensitivity than 2',7'-dichlorofluorescein diacetate. The novel 1,3,6-trimethyl BODIPY formed as a biproduct
Wenjie Ye et al.
Journal of the American Chemical Society, 131(17), 6114-6123 (2009-04-10)
The oxidation of guanine to 5-carboxamido-5-formamido-2-iminohydantoin (2-Ih) is shown to be a major transformation in the oxidation of the single-stranded DNA 5-mer d(TTGTT) by m-chloroperbenzoic acid (m-CPBA) and dimethyldioxirane (DMDO) as a model for peracid oxidants and in the oxidation
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