25800
3-氯过氧苯甲酸
technical, ~70% (RT)
别名:
3-氯过氧苯甲酸, MCPBA
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关于此项目
线性分子式:
ClC6H4CO3H
化学文摘社编号:
分子量:
172.57
PubChem Substance ID:
UNSPSC Code:
12352000
Beilstein/REAXYS Number:
608317
MDL number:
SMILES string
OOC(=O)c1cccc(Cl)c1
InChI
1S/C7H5ClO3/c8-6-3-1-2-5(4-6)7(9)11-10/h1-4,10H
InChI key
NHQDETIJWKXCTC-UHFFFAOYSA-N
grade
technical
assay
~70% (RT)
reaction suitability
reagent type: oxidant
impurities
~10% 3-chlorobenzoic acid, ~20% water
mp
69-71 °C (lit.)
storage temp.
2-8°C
Other Notes
用于烯烃环氧化的试剂
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
G.M. Rubottom et al.
Organic Syntheses, 7, 282-282 (1990)
Tatyana Spolitak et al.
Archives of biochemistry and biophysics, 493(2), 184-191 (2009-11-03)
Our previous rapid-scanning stopped-flow studies of the reaction of substrate-free cytochrome P450cam with peracids [T. Spolitak, J.H. Dawson, D.P. Ballou, J. Biol. Chem. 280 (2005) 20300-20309; J. Inorg. Biochem. 100 (2006) 2034-2044; J. Biol. Inorg. Chem. 13 (2008) 599-611] spectrally
Shin Kamijo et al.
Organic letters, 12(18), 4195-4197 (2010-08-26)
The direct oxidation of ether sp(3) C-H bonds using the new reagent system mCPBA/CCl(3)CN/MeCN has been developed. CCl(3)CN in MeCN drastically alters the reactivity of m-chloroperbenzoic acid (mCPBA), and chemoselective transformation of methyl ethers to ketones was realized under mild
Evelyn B Rodriguez et al.
Journal of food science, 74(9), C674-C682 (2010-05-25)
To gain a better understanding of the reactions and the underlying mechanisms of the oxidative degradation of lycopene, the products formed by epoxidation with m-chloroperbenzoic acid (MCPBA), oxidative cleavage with KMnO(4), and autoxidation in low-moisture and aqueous model systems, under
Wenjie Ye et al.
Journal of the American Chemical Society, 131(17), 6114-6123 (2009-04-10)
The oxidation of guanine to 5-carboxamido-5-formamido-2-iminohydantoin (2-Ih) is shown to be a major transformation in the oxidation of the single-stranded DNA 5-mer d(TTGTT) by m-chloroperbenzoic acid (m-CPBA) and dimethyldioxirane (DMDO) as a model for peracid oxidants and in the oxidation
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