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26226

3-氯苯丙酮

Name: 3-氯苯丙酮
Brand: SIAL

purum, ≥97.5% (HPLC)

别名:

β-氯苯丙酮, 3-氯-1-苯基-1-丙酮

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关于此项目

线性分子式:

ClCH₂CH₂COC₆H₅

化学文摘社编号:

936-59-4

分子量:

168.62

EC Number:

213-317-6

UNSPSC Code:

12352100

PubChem Substance ID:

24855869

Beilstein/REAXYS Number:

2043580

MDL number:

MFCD00000990

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属性

grade

purum

assay

≥97.5% (HPLC)

bp

113-115 °C/4 mmHg (lit.)

mp

48-50 °C

SMILES string

ClCCC(=O)c1ccccc1

InChI

1S/C9H9ClO/c10-7-6-9(11)8-4-2-1-3-5-8/h1-5H,6-7H2

InChI key

KTJRGPZVSKWRTJ-UHFFFAOYSA-N

说明

Application

不稳定苯基乙烯基酮的前体

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存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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分析证书(COA)

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Synthesis of enantiopure glycidol derivatives via a one-pot two-step enzymatic cascade.

Yu-Chang Liu et al.

Organic & biomolecular chemistry, 13(7), 2146-2152 (2014-12-23)

Styrene monooxygenase (SMO) can catalyze the kinetic resolution of secondary allylic alcohols to provide enantiopure glycidol derivatives. To overcome the low theoretical yield of kinetic resolution, we designed a one-pot two-step enzymatic cascade using prochiral α,β-unsaturated ketones as the substrates.