27350
辛可尼丁
purum, ≥98.0% (dried material, NT)
别名:
金鸡尼丁
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关于此项目
经验公式（希尔记法）:
C19H22N2O
化学文摘社编号:
分子量:
294.39
EC Number:
207-622-3
UNSPSC Code:
12352005
PubChem Substance ID:
Beilstein/REAXYS Number:
89690
MDL number:
grade
purum
assay
≥98.0% (dried material, NT)
optical activity
[α]20/D −106±4°, c = 1% in ethanol
impurities
≤15% hydrocinchonine (HPLC), ≤5% quinine (HPLC)
ign. residue
≤0.1%
loss
≤1% loss on drying, 110 °C
mp
204-206 °C (lit.), ~205 °C
SMILES string
O[C@@H]([C@@H]1C[C@@H]2CCN1C[C@@H]2C=C)c3ccnc4ccccc34
InChI
1S/C19H22N2O/c1-2-13-12-21-10-8-14(13)11-18(21)19(22)16-7-9-20-17-6-4-3-5-15(16)17/h2-7,9,13-14,18-19,22H,1,8,10-12H2/t13-,14-,18-,19+/m0/s1
InChI key
KMPWYEUPVWOPIM-KODHJQJWSA-N
Gene Information
human ... CYP2D6(1565)
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1A
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type N95 (US)
法规信息
新产品
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Simon Diezi et al.
Journal of the American Chemical Society, 128(12), 4048-4057 (2006-03-23)
In the Pt-catalyzed hydrogenation of 1,1,1-trifluoro-2,4-diketones, addition of trace amounts of cinchonidine, O-methyl-cinchonidine, or (R,R)-pantoyl-naphthylethylamine induces up to 93% ee and enhances the chemoselectivity up to 100% in the hydrogenation of the activated carbonyl group to an OH function. A
Pierrick Nun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(12), 3773-3779 (2012-02-11)
The asymmetric alkylation of Schiff bases under basic conditions in a ball mill was performed. The starting Schiff bases of glycine were prepared beforehand by milling protected glycine hydrochloride and benzophenone imine, in the absence of solvent. The Schiff base
Erik Schmidt et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(7), 2181-2192 (2009-12-30)
The preparation of stable metal nanoparticles requires a strong interaction between the (organic) stabilizer and the metal surface that might alter the catalytic properties. This behavior has been described as "poisoning" since the stabilizer normally decreases the catalytic activity due