28314
2-氰乙基 N,N,N′,N′-四异丙基亚磷酰二胺
purum, ≥98.0% (31P-NMR)
别名:
双(二异丙基氨基)(2-氰乙氧基)膦
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关于此项目
线性分子式:
{[(CH3)2CH]2N}2POCH2CH2CN
化学文摘社编号:
分子量:
301.41
PubChem Substance ID:
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
3590103
MDL number:
grade
purum
assay
≥98.0% (31P-NMR)
refractive index
n20/D 1.470
bp
100 °C/0.5 mmHg (lit.)
density
0.949 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CC(C)N(C(C)C)P(OCCC#N)N(C(C)C)C(C)C
InChI
1S/C15H32N3OP/c1-12(2)17(13(3)4)20(19-11-9-10-16)18(14(5)6)15(7)8/h12-15H,9,11H2,1-8H3
InChI key
RKVHNYJPIXOHRW-UHFFFAOYSA-N
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Other Notes
用于通过亚磷酸盐法合成核苷酸的亚磷酰化试剂；其他化合物的亚磷酰化
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3 - Skin Sens. 1B
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
119.3 °F - closed cup
flash_point_c
48.5 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
W. Bannwarth et al.
Helvetica Chimica Acta, 71, 1517-1517 (1988)
Y. Jl et al.
Tetrahedron, 46, 487-487 (1990)
W. Bannwarth et al.
Helvetica Chimica Acta, 70, 175-175 (1987)
Improved synthesis of (Pri2 N)2POCH2CH2CN.
J Nielsen et al.
Nucleic acids research, 15(8), 3626-3626 (1987-04-24)
M Morillo et al.
Lipids, 31(5), 541-546 (1996-05-01)
A simple chemical method for the synthesis of 1,2-diacyl-sn-glycerophosphatidylserine (PS), with the same fatty acid composition in the sn-1 and sn-2 glycerol positions as egg phosphatidylcholine (PC), is described. PS synthesis was carried out by a phosphite-triester approach, using 2-cyanoethyl-N,N,N',N'-tetraisopropylphosphorodiamidite
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