28553
氰基膦酸二乙酯
technical, ≥90% (GC)
别名:
DEPC, 氰代磷酸二乙酯
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关于此项目
线性分子式:
(CH3CH2O)2P(O)CN
化学文摘社编号:
分子量:
163.11
EC Number:
220-936-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1768938
MDL number:
grade
technical
assay
≥90% (GC)
refractive index
n20/D 1.403 (lit.)
bp
104-105 °C/19 mmHg (lit.)
density
1.075 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CCOP(=O)(OCC)C#N
InChI
1S/C5H10NO3P/c1-3-8-10(7,5-6)9-4-2/h3-4H2,1-2H3
InChI key
ZWWWLCMDTZFSOO-UHFFFAOYSA-N
General description
Diethyl cyanophosphonate is a nerve agent simulant.
Application
Diethyl cyanophosphonate was used in the synthesis of 4-acylthiol-4-deoxy-4′-demethyl epipodophyllotoxin analogs.
Other Notes
用于肽合成的偶联剂
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
176.0 °F - closed cup
flash_point_c
80 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
[Synthesis and antitumor activities of 4-acylthiol-4-deoxy-4'-demethylepipodophyllotoxin analogues].
Z G Wang et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 27(5), 345-348 (1992-01-01)
This paper describes the synthesis and antitumor activity of 4-acylthiol-4-deoxy-4'-demethylepipodophyllotoxin analogues. 4-Mercapto-4-deoxy-4'-demethylepipodophyllotoxin prepared from 4'-demethylepipodophyllo-toxin with H2S in the presence of BF3.Et2O, was acylated with different acids using diethyl cyanophosphonate and thus, corresponding 4-acylthiol-4-deoxy-4'-demethyl epipodophyllotoxin analogues were synthesized. These compounds
Yoon Jeong Jang et al.
The Analyst, 139(7), 1614-1617 (2014-02-22)
Herein, we present fluorescein as a reversible fluorescent sensor for nerve agent simulants diethylchlorophosphate (DCP), diethyl methylphosphonate (DEMP), and diethyl cyanophosphonate (DECP). The superoxide allows for an "off-on" mechanism to regenerate fluorescein. The order of decrease in fluorescence intensity for
Amino acids and peptides. XXVI. Phosphorus in organic synthesis. XV. Application of diphenyl phosphorazidate (DPPA) and diethyl phosphorocyanidate (DEPC) to the synthesis of the N-terminal decapeptide of gastric inhibitory polypeptide.
Y Hamada et al.
Chemical & pharmaceutical bulletin, 25(2), 224-230 (1977-02-01)