28995
顺式-1,2-环己二醇
puriss., ≥99.0% (GC)
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关于此项目
线性分子式:
C6H10(OH)2
化学文摘社编号:
分子量:
116.16
PubChem Substance ID:
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
1340578
MDL number:
grade
puriss.
assay
≥99.0% (GC)
mp
97-101 °C
SMILES string
O[C@@H]1CCCC[C@@H]1O
InChI
1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6+
InChI key
PFURGBBHAOXLIO-OLQVQODUSA-N
Other Notes
多种对映选择性酶转化反应的原料，如单酰化反应；单氧化反应
法规信息
新产品
此项目有
P. Adlercreutz
Applied Microbiology and Biotechnology, 30, 257-257 (1989)
H.-J. Gais et al.
Tetrahedron Letters, 29, 5743-5743 (1988)
Sigthor Petursson
Carbohydrate research, 338(9), 963-968 (2003-04-12)
The paper reports the tin(II) chloride catalyzed reactions of diazodiphenylmethane with the cis- and trans-1,2-cyclohexanediols and R,S-1,2-propanediol in 1,2-dimethoxyethane and the identification of the monodiphenylmethyl ethers formed. The catalyst is shown to work for both the cis- and trans-cyclohexanediols, but
R J Swift et al.
Applied microbiology and biotechnology, 55(6), 721-726 (2001-08-30)
Benzene dioxygenase (BDO; EC 1.14.12.3) from Pseudomonas putida ML2 dihydroxylates benzene to produce cis-1,2-dihydroxy-cyclohexa-3,5-diene. As well as oxidising benzene and toluene, cell-free extracts of Escherichia coli JM109 expressing recombinant BDO oxidised cyclohexene, 1-methylcyclohexene and 3-methylcyclohexene. In an attempt to construct
Andreas Hartung et al.
The Journal of organic chemistry, 72(26), 10235-10238 (2007-11-16)
Comparison is made between the preparation of trans-1,2-cyclohexanediol in standard glassware (conventional batch production) and in a microreactor (continuous flow production). The reaction sequence involved two exothermic steps where the standard procedure demands slow reagent addition and careful temperature control.
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