29245
N1-[3,5-双(三氟甲基)苄基]-N1-甲基甘氨酰胺 盐酸盐
derivatization grade (GC derivatization), ≥99.0% (HPLC)
别名:
2-氨基-N-[3,5-双(三氟甲基)苄基]-N-甲基乙酰胺 盐酸盐, AMACE 1
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关于此项目
经验公式（希尔记法）:
C12H12F6N2O · HCl
化学文摘社编号:
分子量:
350.69
UNSPSC Code:
41116105
PubChem Substance ID:
MDL number:
grade
derivatization grade (GC derivatization)
assay
≥99.0% (HPLC)
form
solid
reaction suitability
reagent type: derivatization reagent
reaction type: Acylations
SMILES string
Cl.CN(Cc1cc(cc(c1)C(F)(F)F)C(F)(F)F)C(=O)CN
InChI
1S/C12H12F6N2O.ClH/c1-20(10(21)5-19)6-7-2-8(11(13,14)15)4-9(3-7)12(16,17)18;/h2-4H,5-6,19H2,1H3;1H
InChI key
ZBROHYVGMMPRKP-UHFFFAOYSA-N
General description
N1-[3,5-Bis(trifluoromethyl)benzyl]-N1-methylglycinamide hydrochloride (AMACE 1) is an acylation reagent and is generally used in trace organic analysis.
Other Notes
亲核衍生化试剂，用于极为灵敏的 GC-ECD-MS 痕量有机分析
Gang Shao et al.
Journal of chromatography. A, 965(1-2), 233-237 (2002-09-19)
technique that we have termed "bypass HPLC" is introduced as a noncontaminating way to define the retention time of a trace analyte for purification purposes on an HPLC column when the amount of the analyte in real samples is too
R J Lu et al.
Analytical chemistry, 72(8), 1798-1801 (2000-04-28)
Acetamide, 2-amino-N-[[3,5-bis(trifluoromethyl)phenyl]-methyl]-N-methyl-, monohydrochloride, which we have named AMACE1, was synthesized in three steps starting from N-tritylglycine. AMACE1 was coupled via its primary amine group (pKa 8.2) under aqueous conditions to four model analytes for oxidative sugar damage to DNA: glycolate
Gang Shao et al.
Analytical chemistry, 76(11), 3049-3054 (2004-05-29)
As little as 10 pg of standard glycolic acid (glycolate) was detected in a method comprising the following sequence of steps: (1) add glycolate-2,2-d(2) as an internal standard and exchange the carboxylate oxygens in hot HCl/[(18)O]water; (2) form an amide