grade
purum
assay
≥95.0% (GC)
bp
195-197 °C (lit.)
mp
32-41 °C (lit.)
solubility
methanol: soluble 1 g/10 mL, clear to very faintly turbid, colorless
density
0.958 g/mL at 25 °C (lit.)
SMILES string
O=C1CCCCCCC1
InChI
1S/C8H14O/c9-8-6-4-2-1-3-5-7-8/h1-7H2
InChI key
IIRFCWANHMSDCG-UHFFFAOYSA-N
General description
Phase transition from liquid to disordered (plastic) solid phase of cyclooctanone has been studied by dielectric methods.
Application
Cyclooctanone has been used in the preparation of:
- sulfonylbicyclo[3.2.0]heptan-1-ols, sulfonylbicyclo[5.2.0]-nonan-1-ols and sulfonylbicyclo[6.2.0]decan-1-ols
- 14-membered lactones
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
165.2 °F
flash_point_c
74 °C
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Jolanta Swiergiel et al.
The journal of physical chemistry. B, 116(12), 3789-3794 (2012-03-08)
The dielectric studies performed for cyclooctanone in its static dielectric regime have shown that at the phase transition from liquid to disordered (plastic) solid phase of the compound, the following singular phenomena occur: (a) the static permittivity (ε(s)) exhibits a
Synthesis of 14-Membered Lactones from Cyclooctanone.
Aono T and Hesse T.
Helvetica Chimica Acta, 67(6), 1448-1452 (1984)
K Yamada et al.
Chemical & pharmaceutical bulletin, 45(12), 1898-1905 (1998-01-20)
Construction of the AB-ring system of the taxane framework via an A-ring annulation strategy was demonstrated by base-mediated intramolecular aldol reaction of (Z)-2,2-dimethyl-3-(1-methyl-2-oxopropylidene)cyclooctanone, affording the title compound, 1-hydroxy-8,11,11-trimethylbicyclo[5.3.1]undec-7-en-9-one. A cyclization precursor, the tetra-substituted (Z)-alkene, was prepared from the corresponding cyclooctanone
Vishwakarma Singh et al.
The Journal of organic chemistry, 70(3), 973-981 (2005-01-29)
A new and efficient synthesis of a variety of highly embellished bicyclooctenones having an endo-vinyl moiety and their sigmatropic shifts in ground and excited states leading to a stereoselective route to substituted cis-decalins and diquinane frameworks have been described. Functionalized
F E Harvey et al.
Brain research bulletin, 13(4), 541-547 (1984-10-01)
Female mice were reared in observation incubators from day 1 of life for three weeks. During that time they were continuously exposed to the odors of either cyclooctanone, adult male mouse urine or distilled water. The growth rate was temporarily
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