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29819

环戊烯-1-羧酸甲酯

Name: 环戊烯-1-羧酸甲酯
Brand: SIAL

purum, ≥95.0% (GC)

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线性分子式:

C₅H₇CO₂CH₃

化学文摘社编号:

25662-28-6

分子量:

126.15

UNSPSC Code:

12352100

Beilstein/REAXYS Number:

2040162

MDL number:

MFCD00239506

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grade

purum

assay

≥95.0% (GC)

refractive index

n20/D 1.4660 (lit.), n20/D 1.467

bp

76-78 °C/9 mmHg (lit.)

density

1.031 g/mL at 20 °C (lit.)

SMILES string

COC(=O)C1=CCCC1

InChI

1S/C7H10O2/c1-9-7(8)6-4-2-3-5-6/h4H,2-3,5H2,1H3

InChI key

VTYCAXIAUKEGBQ-UHFFFAOYSA-N

General description

Asymmetric oxidative Heck reaction of methyl 1-cyclopentene-1-carboxylate and phenyl boronic acid using Pd-ligand complexes has been reported.

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Asymmetric intermolecular boron Heck-type reactions via oxidative palladium(II) catalysis with chiral tridentate NHC-amidate-alkoxide ligands.

Kyung Soo Yoo et al.

The Journal of organic chemistry, 75(1), 95-101 (2009-12-04)

Chiral dimeric tridentate NHC-amidate-alkoxide palladium(II) complexes, 3a and 3b, effected oxidative boron Heck-type reactions of aryl boronic acids with both acyclic and cyclic alkenes at room temperature to afford the corresponding coupling products with high enantioselectivities. The high degree of

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