31293-M
硫酸铜 五水合物
puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99-102%
别名:
Cupric sulfate 五水合物, 硫酸，铜（II）盐（1：1）五水合物
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关于此项目
线性分子式:
CuSO4 · 5H2O
化学文摘社编号:
分子量:
249.69
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-847-6
MDL number:
Assay:
99-102%
Form:
crystalline
agency
USP/NF, reag. ISO, reag. Ph. Eur.
vapor pressure
7.3 mmHg ( 25 °C)
grade
ACS reagent, puriss. p.a.
assay
99-102%
form
crystalline
impurities
≤0.005% in water insoluble matters, ≤10 mg/kg total nitrogen (N)
pH
3.7-4.5 (20 °C, 5%)
mp
110 °C (dec.) (lit.)
anion traces
chloride (Cl-): ≤10 mg/kg
cation traces
As: ≤0.00005%, Ca: ≤0.001%, Cd: ≤0.001%, Co: ≤0.001%, Fe: ≤0.002%, K: ≤0.001%, Mg: ≤0.0005%, Na: ≤0.002%, Ni: ≤0.002%, Pb: ≤0.002%, Zn: ≤0.030%
SMILES string
O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O
InChI
1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
InChI key
JZCCFEFSEZPSOG-UHFFFAOYSA-L
General description
Copper(II) sulfate pentahydrate (CuSO4·5H2O, Blue vitriol) is a hydrated copper(II) salt. It undergoes hydrothermal reactions with the tripodal ligands to afford metal-organic frameworks (MOFs). CuSO4·5H2O along with metallic copper was employed as a catalyst for the synthesis of different ligand-arm functionalized azoamides. On heating above 560°C, it decomposes to CuO.
Application
Copper(II) sulfate pentahydrate may be employed in the following studies:
- As a catalyst for the acetylation of alcohols and phenols under solvent-free conditions.
- To compose the electrolyte for the electrodeposition of Cu-Zn-Sn precursors, required for the preparation of Cu2ZnSnS4 (CZTS) thin films.
- As catalyst for the dehydration of alcohols.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
Damijana Urankar et al.
Journal of combinatorial chemistry, 10(6), 981-985 (2008-10-17)
Azoamides, previously established as bioactive intracellular GSH-depleting agents, were decorated with a terminal alkyne moiety to 4 and then were transformed, by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC), into different ligand-arm functionalized azoamides 6. Azides 5 having ligand-arms amenable for binding to