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Merck
CN

320528

磺酰氯

97%

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线性分子式:
SO2Cl2
化学文摘社编号:
分子量:
134.97
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
232-245-6
MDL number:
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产品名称

磺酰氯, 97%

InChI key

YBBRCQOCSYXUOC-UHFFFAOYSA-N

InChI

1S/Cl2O2S/c1-5(2,3)4

SMILES string

ClS(Cl)(=O)=O

vapor density

4.7 (vs air)

vapor pressure

100 mmHg ( 17.8 °C)
105 mmHg ( 20 °C)

assay

97%

form

liquid

refractive index

n20/D 1.443 (lit.)

bp

68-70 °C (lit.)

mp

−54 °C (lit.)

density

1.665 g/mL at 20 °C (lit.)

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pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Eye Dam. 1 - Skin Corr. 1C - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chlorinations with sulfuryl chloride. I. The peroxide-catalyzed chlorination of hydrocarbons.
Kharasch MS and Brown HC.
Journal of the American Chemical Society, 61(8), 2142-2150 (1939)
Derek R Boyd et al.
Organic & biomolecular chemistry, 12(13), 2128-2136 (2014-02-27)
Monocyclic allylic cis-1,2-diols reacted with sulfuryl chloride at 0 °C in a regio- and stereo-selective manner to give 2-chloro-1-sulfochloridates, which were hydrolysed to yield the corresponding trans-1,2-chlorohydrins. At -78 °C, with very slow addition of sulfuryl chloride, cyclic sulfates were
Highly regioselective ortho-chlorination of phenol with sulfuryl chloride in the presence of amines.
Gnaim JM and Sheldon RA.
Tetrahedron Letters, 36(22), 3893-3896 (1995)
Chlorination of Dimethyl Sulfide and Some of Its Derivatives with Sulfuryl Chloride and Thionyl Chloride1.
Truce WE, et al.
Journal of the American Chemical Society, 74(14), 3594-3599 (1952)
The chlorination of active hydrogen compounds with sulfuryl chloride. I. Ketones.
Wyman DP and Kaufman PR.
The Journal of Organic Chemistry, 29(7), 1956-1960 (1964)

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