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经验公式(希尔记法):
C15H12F4N4O7S
化学文摘社编号:
分子量:
468.34
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
6673850
InChI
1S/C15H12F4N4O7S/c1-28-11(24)7-4-2-3-5-8(7)31(26,27)23-15(25)22-14-20-9(29-12(16)17)6-10(21-14)30-13(18)19/h2-6,12-13H,1H3,(H2,20,21,22,23,25)
InChI key
ZTYVMAQSHCZXLF-UHFFFAOYSA-N
SMILES string
COC(=O)c1ccccc1S(=O)(=O)NC(=O)Nc2nc(OC(F)F)cc(OC(F)F)n2
grade
analytical standard
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
Quality Level
General description
Primisulfuron-methyl belongs to the class of sulfonylurea herbicides.
Application
Primisulfuron-methyl may be used as an analytical reference standard for the determination of the analyte in:
- Surface and groundwater samples by solid-phase extraction (SPE) and high performance liquid chromatography-electrospray ionization-mass spectrometry (HPLC/ESI-MS).
- Tap and leaching water samples by SPE and LC coupled to tandem mass spectrometry (MS/MS) with ESI and selected reaction monitoring (SRM) detection.
- Wine samples by vortex-assisted ionic liquid dispersive liquid–liquid microextraction ((VA-IL-DLLME)) and capillary HPLC.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Vortex-assisted ionic liquid dispersive liquid-liquid microextraction for the determination of sulfonylurea herbicides in wine samples by capillary high-performance liquid chromatography.
Gure A, et al.
Food Chemistry, 170(2-3), 348-353 (2015)
Olivier Cagnac et al.
Plant physiology, 135(3), 1378-1387 (2004-07-13)
The oligopeptide transporter (OPT) family contains nine members in Arabidopsis. While there is some evidence that AtOPTs mediate the uptake of tetra- and pentapeptides, OPT homologs in rice (Oryza sativa; OsGT1) and Indian mustard (Brassica juncea; BjGT1) have been described
Development and validation of a solid-phase extraction method coupled to high-performance liquid chromatography with ultraviolet-diode array detection for the determination of sulfonylurea herbicide residues in bovine milk samples.
Seccia S, et al.
Journal of Chromatography A, 1218(9), 1253-1259 (2011)
Trace analysis of sulfonylurea herbicides in water samples by solid-phase extraction and liquid chromatography-tandem mass spectrometry.
Fenoll J, et al.
Talanta, 101(2-3), 273-282 (2012)
I Braschi et al.
Journal of agricultural and food chemistry, 48(6), 2565-2571 (2000-07-11)
Microbial degradation of the herbicide primisulfuron was investigated using enrichment cultures from contaminated soils and 20 axenic cultures. At neutral pH, no disappearance of the herbicide was detected either in the enrichment cultures or in the growth media of the
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