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Merck
CN

32433

甲基氟嘧磺隆

PESTANAL®, analytical standard

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经验公式(希尔记法):
C15H12F4N4O7S
化学文摘社编号:
分子量:
468.34
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
6673850
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InChI

1S/C15H12F4N4O7S/c1-28-11(24)7-4-2-3-5-8(7)31(26,27)23-15(25)22-14-20-9(29-12(16)17)6-10(21-14)30-13(18)19/h2-6,12-13H,1H3,(H2,20,21,22,23,25)

InChI key

ZTYVMAQSHCZXLF-UHFFFAOYSA-N

SMILES string

COC(=O)c1ccccc1S(=O)(=O)NC(=O)Nc2nc(OC(F)F)cc(OC(F)F)n2

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

General description

Primisulfuron-methyl belongs to the class of sulfonylurea herbicides.

Application

Primisulfuron-methyl may be used as an analytical reference standard for the determination of the analyte in:
  • Surface and groundwater samples by solid-phase extraction (SPE) and high performance liquid chromatography-electrospray ionization-mass spectrometry (HPLC/ESI-MS).
  • Tap and leaching water samples by SPE and LC coupled to tandem mass spectrometry (MS/MS) with ESI and selected reaction monitoring (SRM) detection.
  • Wine samples by vortex-assisted ionic liquid dispersive liquid–liquid microextraction ((VA-IL-DLLME)) and capillary HPLC.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Vortex-assisted ionic liquid dispersive liquid-liquid microextraction for the determination of sulfonylurea herbicides in wine samples by capillary high-performance liquid chromatography.
Gure A, et al.
Food Chemistry, 170(2-3), 348-353 (2015)
Olivier Cagnac et al.
Plant physiology, 135(3), 1378-1387 (2004-07-13)
The oligopeptide transporter (OPT) family contains nine members in Arabidopsis. While there is some evidence that AtOPTs mediate the uptake of tetra- and pentapeptides, OPT homologs in rice (Oryza sativa; OsGT1) and Indian mustard (Brassica juncea; BjGT1) have been described
Development and validation of a solid-phase extraction method coupled to high-performance liquid chromatography with ultraviolet-diode array detection for the determination of sulfonylurea herbicide residues in bovine milk samples.
Seccia S, et al.
Journal of Chromatography A, 1218(9), 1253-1259 (2011)
Trace analysis of sulfonylurea herbicides in water samples by solid-phase extraction and liquid chromatography-tandem mass spectrometry.
Fenoll J, et al.
Talanta, 101(2-3), 273-282 (2012)
I Braschi et al.
Journal of agricultural and food chemistry, 48(6), 2565-2571 (2000-07-11)
Microbial degradation of the herbicide primisulfuron was investigated using enrichment cultures from contaminated soils and 20 axenic cultures. At neutral pH, no disappearance of the herbicide was detected either in the enrichment cultures or in the growth media of the

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