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Merck
CN

32530

二乙基硫醚

puriss., ≥99.0% (GC)

别名:

1,1 & # 8242;硫代二氯乙烷, NSC 75157, 乙硫醚

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线性分子式:
(C2H5)2S
化学文摘社编号:
分子量:
90.19
EC Number:
206-526-9
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1696909
MDL number:
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vapor pressure

105 mmHg ( 37.7 °C)

grade

puriss.

assay

≥99.0% (GC)

refractive index

n20/D 1.442

bp

90-92 °C (lit.)

mp

−100 °C (lit.)

density

0.837 g/mL at 25 °C (lit.)

SMILES string

CCSCC

InChI

1S/C4H10S/c1-3-5-4-2/h3-4H2,1-2H3

InChI key

LJSQFQKUNVCTIA-UHFFFAOYSA-N

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General description

Diethyl sulfide is a simulant for chemical agent mustard gas. Photooxidation of gaseous diethyl sulfide over TiO2 in a flow reactor was investigated.

Application

Diethyl sulfide was employed as ancillary ligand in the preparation of brightly luminescent Pt(II) pincer complexes.

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

15.8 °F - closed cup

flash_point_c

-9 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Lot/Batch Number

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Anton M Prokhorov et al.
Journal of the American Chemical Society, 136(27), 9637-9642 (2014-06-18)
A series of three Pt(II) complexes with a doubly cyclometalating terdentate ligand L1, L1H2 = 3,6-bis(p-anizolyl)-2-carboranyl-pyridine, and diethyl sulfide (1), triphenylphosphine (2), and t-butylisonitrile (3) as ancillary ligands were synthesized. X-ray diffraction studies of 1 and 2 show a coordination
Gas-phase photocatalytic oxidation of diethyl sulfide over TiO< sub> 2</sub>: kinetic investigations and catalyst deactivation.
Kozlov DV, et al.
Applied Catalysis. B, Environmental, 42(1), 77-87 (2003)
Taylor C Hayward et al.
Journal of chromatography. A, 1105(1-2), 66-70 (2005-09-30)
A recently reported micro-flame photometric detector (microFPD) has been examined in greater detail for its sulfur response characteristics. While supporting an "upside down" flame on a stainless steel capillary burner (delivering oxygen) in a counter flowing stream of premixed hydrogen
Femtochemistry uncovers the nature of electron transfer reactions.
A W Castleman et al.
Proceedings of the National Academy of Sciences of the United States of America, 96(8), 4219-4220 (1999-04-14)
Andrea Belancic Majcenovic et al.
Journal of agricultural and food chemistry, 50(23), 6653-6658 (2002-10-31)
Ethanethiol and diethyl disulfide (DEDS) most often occurred at levels above their olfactive threshold in wines with nauseous sulfur-linked smells. As ethanethiol is very oxidizable and chemically reactive, a stable isotopic dilution analysis of both ethanethiol and its disulfide in

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