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Merck
CN

33310

Sigma-Aldrich

2,3-二氨基吡啶

technical, ≥98.0% (NT)

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经验公式(希尔记法):
C5H7N3
化学文摘社编号:
分子量:
109.13
Beilstein:
109869
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
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等级

technical

方案

≥98.0% (NT)

mp

110-115 °C (lit.)
110-115 °C

溶解性

methanol: soluble 1 g/10 mL

SMILES字符串

Nc1cccnc1N

InChI

1S/C5H7N3/c6-4-2-1-3-8-5(4)7/h1-3H,6H2,(H2,7,8)

InChI key

ZZYXNRREDYWPLN-UHFFFAOYSA-N

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一般描述

2,3-Diaminopyridine forms charge transfer complexes with the Π-electron acceptors chloranilic acid and dihydroxy-p-benzoquinone, which were investigated spectrophotometrically in ethanol.

应用

2,3-Diaminopyridine was employed:
  • as an electrochemical substrate in voltammetric enzyme-linked immunoassay system
  • in the preparation of Cu2+-selective sensors
  • in the general synthesis of 1-phenyl-2-(4-aryl-1,3,4,5-tetrahydropyrido[2,3-b][1,4]diazepin-2-ylidene)-ethanones

象形图

Exclamation mark

警示用语:

Warning

危险声明

预防措施声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

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Lok P Singh et al.
Talanta, 64(2), 313-319 (2008-10-31)
Plasticized membranes using Schiff Base complexes, derived from 2,3-diaminopyridine and o-vanilin have been prepared and explored as Cu(2+)-selective sensors. Effect of various plasticizers viz., dibutyl phthalate (DBP), dioctylphthalate (DOP), chloronaphthalene (CN), tri-n-butylphosphate (TBP) etc. and anion excluder, sodium tetraphenylborate (NaTPB)
Khairia M Al-Ahmary
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 117, 635-644 (2013-10-12)
Charge transfer (CT) complexes formed between 2,3-aminopyridine (2,3-DAP) as electron donor with the π-electron acceptors chloranilic acid (CHA) and dihydroxy-p-benzoquinone (DHBQ) were investigated spectrophotometrically in ethanol. Minimum-maximum absorbance method has been used for estimating the formation constants of the charge
Madhukar Hemamalini et al.
Acta crystallographica. Section E, Structure reports online, 67(Pt 11), o3122-o3122 (2012-01-06)
In the title hydrated mol-ecular salt, C(5)H(8)N(3) (+)·C(7)H(5)O(6)S(-)·H(2)O, the ion pairs and water mol-ecules are connected by N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds, thereby forming a three-dimensional network. There is an intra-molecular O-H⋯O hydrogen bond in the 3-carb-oxy-4-hy-droxy-benzene-sulfonate anion, which
H Liszkiewicz et al.
Die Pharmazie, 61(6), 517-521 (2006-07-11)
A two-step, general synthesis of 1-phenyl-2-(4-aryl-1,3,4,5-tetrahydropyrido[2,3-b][1,4]diazepin-2-ylidene)-ethanones 3-9 is presented. This synthesis employs a condensation of 2,3-diaminopyridine with benzoylacetone followed by a basic-activated cyclization reaction with substituted benzaldehydes for final closure of the seven-membered ring. Molecular diversity is fixed by appropriate
G David et al.
Brain research, 339(1), 57-65 (1985-07-22)
The mechanisms underlying the induction of afterdischarges at presynaptic nerve terminals by convulsant aminopyridines and their suppression by the anticonvulsant drug phenytoin were studied at the frog neuromuscular preparation. Addition of aminopyridine to the perfusing solution induced the appearance of

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