等级
technical
方案
≥98.0% (NT)
mp
110-115 °C (lit.)
110-115 °C
溶解性
methanol: soluble 1 g/10 mL
SMILES字符串
Nc1cccnc1N
InChI
1S/C5H7N3/c6-4-2-1-3-8-5(4)7/h1-3H,6H2,(H2,7,8)
InChI key
ZZYXNRREDYWPLN-UHFFFAOYSA-N
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一般描述
2,3-Diaminopyridine forms charge transfer complexes with the Π-electron acceptors chloranilic acid and dihydroxy-p-benzoquinone, which were investigated spectrophotometrically in ethanol.
应用
2,3-Diaminopyridine was employed:
- as an electrochemical substrate in voltammetric enzyme-linked immunoassay system
- in the preparation of Cu2+-selective sensors
- in the general synthesis of 1-phenyl-2-(4-aryl-1,3,4,5-tetrahydropyrido[2,3-b][1,4]diazepin-2-ylidene)-ethanones
警示用语:
Warning
危险声明
预防措施声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Lok P Singh et al.
Talanta, 64(2), 313-319 (2008-10-31)
Plasticized membranes using Schiff Base complexes, derived from 2,3-diaminopyridine and o-vanilin have been prepared and explored as Cu(2+)-selective sensors. Effect of various plasticizers viz., dibutyl phthalate (DBP), dioctylphthalate (DOP), chloronaphthalene (CN), tri-n-butylphosphate (TBP) etc. and anion excluder, sodium tetraphenylborate (NaTPB)
Khairia M Al-Ahmary
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 117, 635-644 (2013-10-12)
Charge transfer (CT) complexes formed between 2,3-aminopyridine (2,3-DAP) as electron donor with the π-electron acceptors chloranilic acid (CHA) and dihydroxy-p-benzoquinone (DHBQ) were investigated spectrophotometrically in ethanol. Minimum-maximum absorbance method has been used for estimating the formation constants of the charge
Madhukar Hemamalini et al.
Acta crystallographica. Section E, Structure reports online, 67(Pt 11), o3122-o3122 (2012-01-06)
In the title hydrated mol-ecular salt, C(5)H(8)N(3) (+)·C(7)H(5)O(6)S(-)·H(2)O, the ion pairs and water mol-ecules are connected by N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds, thereby forming a three-dimensional network. There is an intra-molecular O-H⋯O hydrogen bond in the 3-carb-oxy-4-hy-droxy-benzene-sulfonate anion, which
H Liszkiewicz et al.
Die Pharmazie, 61(6), 517-521 (2006-07-11)
A two-step, general synthesis of 1-phenyl-2-(4-aryl-1,3,4,5-tetrahydropyrido[2,3-b][1,4]diazepin-2-ylidene)-ethanones 3-9 is presented. This synthesis employs a condensation of 2,3-diaminopyridine with benzoylacetone followed by a basic-activated cyclization reaction with substituted benzaldehydes for final closure of the seven-membered ring. Molecular diversity is fixed by appropriate
G David et al.
Brain research, 339(1), 57-65 (1985-07-22)
The mechanisms underlying the induction of afterdischarges at presynaptic nerve terminals by convulsant aminopyridines and their suppression by the anticonvulsant drug phenytoin were studied at the frog neuromuscular preparation. Addition of aminopyridine to the perfusing solution induced the appearance of
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