33731
三氯乙酸
puriss. p.a., ACS reagent, ≥99.5%
别名:
TCA
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关于此项目
线性分子式:
Cl3CCOOH
化学文摘社编号:
分子量:
163.39
EC Number:
200-927-2
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
970119
MDL number:
InChI key
YNJBWRMUSHSURL-UHFFFAOYSA-N
InChI
1S/C2HCl3O2/c3-2(4,5)1(6)7/h(H,6,7)
SMILES string
OC(=O)C(Cl)(Cl)Cl
grade
ACS reagent, puriss. p.a.
assay
≥99.5%
impurities
≤0.002% heavy metals (as Pb), ≤0.005% water insolubles
ign. residue
≤0.01% (as SO4)
refractive index
n20/D 1.62 (lit.)
bp
196 °C (lit.)
mp
54-58 °C (lit.)
density
1.62 g/mL at 25 °C (lit.)
anion traces
chloride (Cl-): ≤10 mg/kg, nitrate (NO3-): ≤20 mg/kg, phosphate (PO43-): ≤5 mg/kg, sulfate (SO42-): ≤100 mg/kg
cation traces
Cu: ≤5 mg/kg, Fe: ≤10 mg/kg
suitability
complies for appearance of solution
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General description
Trichloroacetic acid (TCA) is a chlorinated acetic acid. It is one of the major metabolite of trichloroethylene (TCE).
Application
传统上用于沉淀蛋白质。用于通过定量沉淀测定蛋白质浓度。用作脱钙剂和显微镜样品的固定剂。
Trichloroacetic acid may be used for the quantification of inorganic phosphorus in various biological samples (serum, urine and stool ash solutions). It may be used for the elimination of acid-soluble and lipid phosphorous during the quantitative estimation of deoxyribonucleic acid, ribonucleic acid and phosphoproteins in animal tissues. 10% trichloroacetic acid may be employed for the preparation of radioactive proteins.
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1A
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
>235.4 °F - closed cup
flash_point_c
> 113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Solubility of albumin in alcohol after precipitation by trichloroacetic acid: a simplified procedure for separation of albumin.
J R DEBRO et al.
Nature, 178(4541), 1067-1067 (1956-11-10)
A method for the determination of desoxyribonucleic acid, ribonucleic acid, and phosphoproteins in animal tissues.
G SCHMIDT et al.
The Journal of biological chemistry, 161, 83-89 (1945-01-01)
A microcolorimetric method for the determination of inorganic phosphorus.
H H TAUSSKY et al.
The Journal of biological chemistry, 202(2), 675-685 (1953-06-01)
S L Herren-Freund et al.
Toxicology and applied pharmacology, 90(2), 183-189 (1987-09-15)
Trichloroethylene (TCE) has previously been shown to be carcinogenic in mouse liver when administered by daily gavage in corn oil. The metabolism of TCE results, in part, in the formation of trichloroacetic acid (TCA) as a major metabolite and dichloroacetic
Inga Müller et al.
PloS one, 9(5), e97285-e97285 (2014-05-27)
Members of the MYC family are the most frequently deregulated oncogenes in human cancer and are often correlated with aggressive disease and/or poorly differentiated tumors. Since patients with MYCN-amplified neuroblastoma have a poor prognosis, targeting MYCN using small molecule inhibitors
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