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33735

二苄基 N,N-二异丙基亚磷酰胺

Name: 二苄基 <I>N</I>,<I>N</I>-二异丙基亚磷酰胺
Brand: SIAL

purum, ≥97.0% (CHN)

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线性分子式:

[(CH₃)₂CH]₂NP(OCH₂C₆H₅)₂

化学文摘社编号:

108549-23-1

分子量:

345.42

UNSPSC Code:

12352100

Beilstein/REAXYS Number:

3616864

MDL number:

MFCD00191988

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属性

grade

purum

assay

≥97.0% (CHN)

refractive index

n20/D 1.535 (lit.)

bp

130 °C/0.55 mmHg (lit.)

density

1.028 g/mL at 25 °C (lit.)

SMILES string

CC(C)N(C(C)C)P(OCc1ccccc1)OCc2ccccc2

InChI

1S/C20H28NO2P/c1-17(2)21(18(3)4)24(22-15-19-11-7-5-8-12-19)23-16-20-13-9-6-10-14-20/h5-14,17-18H,15-16H2,1-4H3

InChI key

ANPWLBTUUNFQIO-UHFFFAOYSA-N

说明

Other Notes

用于由肌醇合成磷酸肌醇的苄酯的亚磷酸化剂

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Chiral synthesis of D- and L-myo-inositol 1,4,5-trisphosphate.

W Tegge et al.

Proceedings of the National Academy of Sciences of the United States of America, 86(1), 94-98 (1989-01-01)

Chiral inositols (D-chiro-inositol from D-pinitol and L-chiro-inositol from L-quebrachitol) were converted to the 3,4-di-O-benzyl ethers, which were selectively benzoylated to yield the 1,2,5-tri-O-benzoyl-3,4-di-O-benzyl-chiro-inositols. The free hydroxyl group in each derivative was inverted by way of the trifluoromethane sulfonate ester to

K.K. Reddy et al.

Tetrahedron Letters, 34, 7869-7869 (1993)