34108
磷酸三丁酯
analytical standard
别名:
TBP, TBPA
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关于此项目
线性分子式:
(CH3(CH2)3O)3PO
化学文摘社编号:
分子量:
266.31
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
204-800-2
Beilstein/REAXYS Number:
1710584
MDL number:
InChI
1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI key
STCOOQWBFONSKY-UHFFFAOYSA-N
SMILES string
CCCCOP(=O)(OCCCC)OCCCC
grade
analytical standard
vapor density
9.2 (vs air)
vapor pressure
27 mmHg ( 178 °C), 7.3 mmHg ( 150 °C)
autoignition temp.
770 °F
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
Quality Level
bp
180-183 °C/22 mmHg (lit.)
mp
−79 °C (lit.)
density
0.979 g/mL at 25 °C (lit.)
application(s)
cleaning products
cosmetics
environmental
food and beverages
personal care
format
neat
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General description
磷酸三丁酯是一种有机磷化合物，可作为阻燃剂和增塑剂广泛应用于多种工业产品中。
Application
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磷酸三丁酯可用作分析标准品，用于测定以下物质中的分析物：
- 室内空气样品，使用活性炭管抽样，然后使用气相色谱-质谱法以及火焰光度法检测
- 人血浆样品，使用固相微萃取，然后使用气相色谱-电感耦合等离子体质谱法
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
293.0 °F - closed cup
flash_point_c
145 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Analysis of organic esters of plasticizer in indoor air by GC- MS and GC- FPD.
Otake T, et al.
Environmental Science & Technology, 35(15), 3099-3102 (2001)
Monika Shah et al.
Journal of chromatography. A, 1103(2), 329-336 (2005-12-13)
A simple and sensitive method for determination of phosphoric acid triesters at trace levels in human plasma sample is described. In this work, solid-phase microextraction (SPME) is employed as a sample preparation procedure for extraction and pre-concentration of alkyl and
Omar Arous et al.
Journal of hazardous materials, 180(1-3), 493-498 (2010-05-19)
In this work, a development of polymeric inclusion membranes for the cations separation is reported. The membrane was made up of cellulose triacetate (CTA) with a tributyl phosphate (TBP) incorporated into the polymer as metal ions carrier. The transport of
Recep Ali Kumbasar
Journal of hazardous materials, 178(1-3), 875-882 (2010-03-17)
The facilitated extraction of Cr(VI) through an emulsion liquid membrane (ELM) was investigated, using tributyl phosphate (TBP) as mobile carrier. The emulsion liquid membrane phase consists of kerosene as diluent, TBP as carrier, SPAN 80 as surfactant and (NH(4))(2)CO(3) solution
Siu Hua Chang et al.
Journal of hazardous materials, 190(1-3), 197-204 (2011-04-16)
The objectives of this work were to select suitable design parameters and optimize the operating parameters of a soybean oil-based bulk liquid membrane (BLM) for Cu(II) removal and recovery from aqueous solutions. The soybean oil-based BLM consists of an aqueous
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