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Merck
CN

35680

2,3-二氯-5,6-二氰基对苯醌

purum, ≥95.0% (RT)

别名:

4,5-二氯-3,6-二氧-1,4-环己二烯-1,2-二甲腈, DDQ

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经验公式(希尔记法):
C8Cl2N2O2
化学文摘社编号:
分子量:
227.00
EC Number:
201-542-2
UNSPSC Code:
12352115
PubChem Substance ID:
Beilstein/REAXYS Number:
747939
MDL number:
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InChI key

HZNVUJQVZSTENZ-UHFFFAOYSA-N

InChI

1S/C8Cl2N2O2/c9-5-6(10)8(14)4(2-12)3(1-11)7(5)13

SMILES string

ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O

grade

purum

assay

≥95.0% (RT)

reaction suitability

reagent type: oxidant

mp

210-215 °C (dec.) (lit.)

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Other Notes

用于氢化芳族化合物脱氢的试剂;用于温和断裂醚类保护基团的试剂
This product has been replaced by 35170-ALDRICH | 2,4-Dichloroaniline ≥97.0% (GC)

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Y. Oikawa et al.
Tetrahedron Letters, 25, 5393-5393 (1984)
A. Oku et al.
Chemistry Letters (Jpn), 165-165 (1993)
DDQ-catalyzed oxidative C--O coupling of sp³ C--H bonds with carboxylic acids.
Hong Yi et al.
ChemSusChem, 5(11), 2143-2146 (2012-11-07)
Yubin Ding et al.
Organic & biomolecular chemistry, 10(21), 4201-4207 (2012-04-24)
Cyanide sensing has attracted increasing interest due to its toxicity and wide use in industrial activities. Herein, we developed three colorimetric cyanide sensors by the modification of the α-position of a dipyrrin chromophore with various carbonyl groups, namely, C(6)F(5)CO, C(6)H(5)CO
K Ganesh et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 92, 46-55 (2012-03-10)
UV-vis, (1)H NMR, FT-IR, mass and fluorescence spectral techniques were employed to investigate the mechanism of interaction of albendazole and trimethoprim with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and to characterize the reaction products. The interaction of DDQ with trimethoprim (TMP) and albenadazole (ALB)

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