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Merck
CN

35680

Sigma-Aldrich

2,3-二氯-5,6-二氰基对苯醌

purum, ≥95.0% (RT)

别名:

4,5-二氯-3,6-二氧-1,4-环己二烯-1,2-二甲腈, DDQ

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关于此项目

经验公式(希尔记法):
C8Cl2N2O2
化学文摘社编号:
分子量:
227.00
Beilstein:
747939
EC 号:
MDL编号:
UNSPSC代码:
12352115
PubChem化学物质编号:
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等级

purum

方案

≥95.0% (RT)

反应适用性

reagent type: oxidant

mp

210-215 °C (dec.) (lit.)

SMILES字符串

ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O

InChI

1S/C8Cl2N2O2/c9-5-6(10)8(14)4(2-12)3(1-11)7(5)13

InChI key

HZNVUJQVZSTENZ-UHFFFAOYSA-N

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其他说明

用于氢化芳族化合物脱氢的试剂;用于温和断裂醚类保护基团的试剂
This product has been replaced by 35170-ALDRICH | 2,4-Dichloroaniline ≥97.0% (GC)

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Y. Oikawa et al.
Tetrahedron Letters, 25, 5393-5393 (1984)
Tetrahedron Letters, 25, 5397-5397 (1984)
Casey C Cosner et al.
Organic letters, 13(8), 2071-2073 (2011-03-15)
A practical, chemoselective oxidation of alcohols employing catalytic quantities of DDQ as the oxidant and Mn(OAc)(3) as the co-oxidant is described. Electron-rich benzylic alcohols are oxidized efficiently to their corresponding carbonyls, but less electron-rich benzylic alcohols remain unchanged. Allylic alcohols
Sheri Madhu et al.
Inorganic chemistry, 50(10), 4392-4400 (2011-04-23)
A series of boron dipyrromethene (BODIPY) dyes containing two aldehyde functional groups at the 3 and 5 positions have been synthesized in low-to-decent yields in two steps. In the first step, the meso-aryl dipyrromethanes were treated with POCl(3) in N,N-dimethylformamide
A. Oku et al.
Chemistry Letters (Jpn), 165-165 (1993)

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