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Merck
CN

35990

2,3-二氯-1,4-萘醌

for spectrophotometric det. of hydrazides, ≥98.0%

别名:

二氯萘醌

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经验公式(希尔记法):
C10H4Cl2O2
化学文摘社编号:
分子量:
227.04
UNSPSC Code:
41116105
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-210-5
Beilstein/REAXYS Number:
1073511
MDL number:
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InChI key

SVPKNMBRVBMTLB-UHFFFAOYSA-N

InChI

1S/C10H4Cl2O2/c11-7-8(12)10(14)6-4-2-1-3-5(6)9(7)13/h1-4H

SMILES string

ClC1=C(Cl)C(=O)c2ccccc2C1=O

description

algaecide

assay

≥98.0% (AT), ≥98.0%

form

powder

quality

for spectrophotometric det. of hydrazides

technique(s)

UV/Vis spectroscopy: suitable

mp

192-195 °C, 194-197 °C (lit.)

Quality Level

General description

2,3-Dichloro-1,4-naphthoquinone is a potent and safe fungicide, and finds application in both agriculture and textile industry. During seed treatment, it is used as a foliage spray and is also an excellent mildew-proofing agent. Furthermore it also resists weathering.

Application

2,3-Dichloro-1,4-naphthoquinone was used in its alkaline form in the colorimetric method, used for the spectrophotometric determination of hydrazides. It may also be used for the spectrophotometric analysis of isoniazid in the presence of its hydrazones.

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

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分析证书(COA)

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Spectrophotometric determination of hydrazides with 2, 3-dichloro-1, 4-napthoquinone.
Plaizier JA
Analytical Chemistry, 48 (11), 1536-1538 (1976)
Spectrophotometric determination of isoniazid in presence of its hydrazones.
Devani MB
Journal of Pharmaceutical Sciences, 67 (5), 661-663 (1978)
2, 3-Dichloro-1, 4-naphthoquinone
Horst WP and Felix EL.
Ind. and Eng. Chem., 35 (12), 1255-1259 (1943)
C A Pritsos et al.
Biochemical pharmacology, 33(23), 3771-3777 (1984-12-01)
The addition of 2,3-dichloro-1,4-naphthoquinone (CNQ) to substrate-depleted, GSH-supplemented rat liver mitochondria resulted in a dose-dependent depletion of reactable suflhydryl groups and a concomitant increase in mitochondrial disulfide content at a ratio of 2 thiols depleted/disulfide generated. The molar ratio of
[Reactions of trialkylamine compounds with 2,3-dichloro-1,4-naphthoquinone].
H J Kallmayer et al.
Die Pharmazie, 57(9), 648-649 (2002-10-09)

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