36323
(S)-2-哌啶酮-6-羧酸
≥95.0% (HPLC)
别名:
6-氧代-L-哌啶甲酸, (S)-2-哌啶酮-6-甲酸, L-Pyrohomoglutamic acid
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关于此项目
经验公式（希尔记法）:
C6H9NO3
化学文摘社编号:
分子量:
143.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
≥95.0% (HPLC)
产品名称
(S)-2-哌啶酮-6-羧酸, ≥95.0% (HPLC)
InChI
1S/C6H9NO3/c8-5-3-1-2-4(7-5)6(9)10/h4H,1-3H2,(H,7,8)(H,9,10)/t4-/m0/s1
SMILES string
OC(=O)[C@@H]1CCCC(=O)N1
InChI key
FZXCPFJMYOQZCA-BYPYZUCNSA-N
assay
≥95.0% (HPLC)
impurities
≤5.0% water
functional group
carboxylic acid
Quality Level
Application
(S)-6-Oxo-2-piperidinecarboxylic acid can be used as a reactant to synthesize:
- Functionalized β-lactam N-heterocycles via carboxymethylproline synthase catalyzed cyclization reactions. Pro-(S)-C5 branched [4.3.1] aza-amide bicycles as potential inhibitors for FK506-binding proteins.
- Ethyl (S)-2-(6-oxopiperidin-2-yl)acetate, which is reduced using LiBH4 to produce optically pure hydroxymethyl lactams.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Carboxymethylproline synthase catalysed syntheses of functionalised N-heterocycles
Hamed RB, et al.
Chemical Communications (Cambridge, England), 46(9), 1413-1415 (2010)
Preparation of optically pure ω-hydroxymethyl lactams
Huang S-B, et al.
Synthetic Communications, 19(20), 3485-3496 (1989)
Rational Design and Asymmetric Synthesis of Potent and Neurotrophic Ligands for FK506-Binding Proteins (FKBPs)
Pomplun S, et al.
Angewandte Chemie (International ed. in English), 54(1), 345-348 (2015)
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