37281
2,3-二氢苯并呋喃
purum, ≥97.0% (GC)
别名:
氯杀鼠灵
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关于此项目
经验公式（希尔记法）:
C8H8O
化学文摘社编号:
分子量:
120.15
EC Number:
207-817-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
111928
MDL number:
grade
purum
assay
≥97.0% (GC)
refractive index
n20/D 1.549
bp
188-189 °C (lit.)
solubility
alcohols: soluble(lit.), carbon disulfide: soluble(lit.), chloroform: soluble(lit.), diethyl ether: soluble(lit.)
density
1.065 g/mL at 25 °C (lit.)
SMILES string
C1Cc2ccccc2O1
InChI
1S/C8H8O/c1-2-4-8-7(3-1)5-6-9-8/h1-4H,5-6H2
InChI key
HBEDSQVIWPRPAY-UHFFFAOYSA-N
Gene Information
human ... CYP1A2(1544)
General description
Biotransformation of 2,3-dihydrobenzofuran using intact cells of Pseudomonas putida UV4 has been investigated. 2,3-Dihydrobenzofuran is the intermediate formed during catalytic hydrodeoxygenations (HDOs) of benzofuran. Reaction of o-bromophenyl allyl ether and N-allyl o-bromoacetanilide with tributyltin hydride in the presence of activated olefin compounds is reported to yield 2, 3-dihydrobenzofuran derivatives. 2,3-Dihydrobenzofuran is reported to participate in the HDO network of benzofuran over alumina-supported Ni-Mo sulfided and reduced catalysts.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
152.6 °F - closed cup
flash_point_c
67 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Investigation of the Reaction Network of Benzofuran Hydrodeoxygenation over Sulfided and Reduced Ni-Mo/Al2O3 Catalysts.
Bunch AY and Ozkan US.
J. Catal., 206(2), 177-187 (2002)
Double carbon-carbon bond formations via both intramolecular and intermolecular radical reactions with tributyltin hydride to give 2, 3-dihydrobenzofuran and 2, 3-dihydroindole derivatives.
Togo H and Kikuchi O.
Tetrahedron Letters, 29(33), 4133-4134 (1988)
Catalytic hydrodeoxygenation of benzofuran and o-ethylphenol.
Lee C-L and Ollis DF.
J. Catal., 87(2), 325-331 (1984)
Guo-Hua Chu et al.
Bioorganic & medicinal chemistry letters, 15(23), 5114-5119 (2005-10-06)
Two novel chemical classes of kappa opioid receptor agonists, chroman-2-carboxamide derivatives and 2,3-dihydrobenzofuran-2-carboxamide derivatives, were synthesized. These agents exhibited high and selective affinity for the kappa opioid receptor.
Structures and stereochemical assignments of some novel chiral synthons derived from the biotransformation of 2, 3-dihydrobenzofuran and benzofuran by Pseudomonas putida.
Boyd DR, et al.
Tetrahedron Asymmetry, 4(6), 1307-1324 (1993)
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