40765
(-)-Tröger′s base
LiChropur™, ≥99.0%
别名:
(-)-Tröger 碱
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关于此项目
经验公式(希尔记法):
C17H18N2
化学文摘社编号:
分子量:
250.34
Beilstein:
88611
MDL编号:
UNSPSC代码:
41116105
PubChem化学物质编号:
等级
derivatization grade ((chiral))
质量水平
方案
≥99.0% (sum of enantiomers, HPLC)
≥99.0%
旋光性
[α]20/D −283±4°, c = 0.3% in hexane
光学纯度
enantiomeric ratio: ≥99.5:0.5 (HPLC)
质量
LiChropur™
mp
127-131 °C
SMILES字符串
Cc1ccc2[N@@H]3C[N@H](Cc2c1)c4ccc(C)cc4C3
InChI
1S/C17H18N2/c1-12-3-5-16-14(7-12)9-18-11-19(16)10-15-8-13(2)4-6-17(15)18/h3-8H,9-11H2,1-2H3
InChI key
SXPSZIHEWFTLEQ-UHFFFAOYSA-N
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一般描述
Tröger base (TB) is a chiral heterocyclic amine with chirality due to the presence of two stereogenic nitrogen atoms.
应用
It was used as an standard analyte for testing the enantioseparation capability of the chiral stationary phase column; in a study to understand the covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column.
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
法律信息
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Xiaoli Dong et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 875(1), 317-322 (2008-09-02)
A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix within the confine of a 50-microm i.d. bare fused silica capillary. Several pairs of enantiomers including neutral
Resolution, asymmetric transformation, and configuration of Troger's base. Application of Troger's base as a chiral solvating agent.
Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard
Organic Chemistry, 56, 485-487 (1991)
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