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Merck
CN

40765

Supelco

(-)-Tröger′s base

LiChropur, ≥99.0%

别名:

(-)-Tröger 碱

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关于此项目

经验公式(希尔记法):
C17H18N2
化学文摘社编号:
分子量:
250.34
Beilstein:
88611
MDL编号:
UNSPSC代码:
41116105
PubChem化学物质编号:
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等级

derivatization grade ((chiral))

质量水平

方案

≥99.0% (sum of enantiomers, HPLC)
≥99.0%

旋光性

[α]20/D −283±4°, c = 0.3% in hexane

光学纯度

enantiomeric ratio: ≥99.5:0.5 (HPLC)

质量

LiChropur

mp

127-131 °C

SMILES字符串

Cc1ccc2[N@@H]3C[N@H](Cc2c1)c4ccc(C)cc4C3

InChI

1S/C17H18N2/c1-12-3-5-16-14(7-12)9-18-11-19(16)10-15-8-13(2)4-6-17(15)18/h3-8H,9-11H2,1-2H3

InChI key

SXPSZIHEWFTLEQ-UHFFFAOYSA-N

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一般描述

Tröger base (TB) is a chiral heterocyclic amine with chirality due to the presence of two stereogenic nitrogen atoms.

应用

It was used as an standard analyte for testing the enantioseparation capability of the chiral stationary phase column; in a study to understand the covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column.

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

其他说明

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Xiaoli Dong et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 875(1), 317-322 (2008-09-02)
A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix within the confine of a 50-microm i.d. bare fused silica capillary. Several pairs of enantiomers including neutral
Resolution, asymmetric transformation, and configuration of Troger's base. Application of Troger's base as a chiral solvating agent.
Wilen, Samuel H., Jian Zhong Qi, and Paul G. Williard
Organic Chemistry, 56, 485-487 (1991)

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