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Merck
CN

41610

硫酸二甲酯

≥99.0% (GC), liquid, puriss. p.a.

别名:

二甲基硫酸酯

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关于此项目

线性分子式:
(CH3O)2SO2
化学文摘社编号:
77-78-1
分子量:
126.13
NACRES:
NA.21
PubChem Substance ID:
57650074
UNSPSC Code:
12352100
EC Number:
201-058-1
MDL number:
MFCD00008416
Beilstein/REAXYS Number:
635994

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产品名称

硫酸二甲酯, puriss. p.a., ≥99.0% (GC)

InChI key

VAYGXNSJCAHWJZ-UHFFFAOYSA-N

InChI

1S/C2H6O4S/c1-5-7(3,4)6-2/h1-2H3

SMILES string

COS(=O)(=O)OC

vapor density

4.3 (vs air)

vapor pressure

0.7 mmHg ( 25 °C)

grade

puriss. p.a.

assay

≥99.0% (GC)

form

liquid

autoignition temp.

923 °F

impurities

≤0.4% free acid (as H2SO4)

ign. residue

≤0.02%

refractive index

n20/D 1.386 (lit.)
n20/D 1.387

bp

188 °C (lit.)

mp

−32 °C (lit.)

solubility

ethanol: 0.26 g/mL, clear, colorless
diethyl ether: 1.3 g/5mL, clear, colorless

density

1.333 g/mL at 25 °C (lit.)

cation traces

Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤20 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Zn: ≤1 mg/kg

Quality Level

200

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相关类别

General description

Dimethyl sulfate is the dimethyl ester of sulfuric acid. It undergoes hydrolysis to afford monomethyl sulfate. It is found as contaminant in fly ash and in airborne particulate matter generated during the coal combustion processes.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

181.4 °F - closed cup

flash_point_c

83 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL0259
BCCH2096
BCCH6719
BCCH7474
BCCH2924

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J D McGhee et al.
Proceedings of the National Academy of Sciences of the United States of America, 76(5), 2133-2137 (1979-05-01)
We have measured the effect of the histones in the nucleosome core particle on methylation of purines in nucleosome DNA by dimethyl sulfate. By using 32P terminally labeled nucleosome cores, we have examined the pattern of strand cleavage at methylated
M L Lee et al.
Science (New York, N.Y.), 207(4427), 186-188 (1980-01-11)
Dimethyl sulfate and its hydrolysis product monomethyl sulfate have been found at concentrations as high as 830 parts per million in fly ash and in airborne particulate matter from coal combustion processes. This discovery poses a new environmental problem because
Kwang Sun Ryu et al.
The journal of physical chemistry. B, 111(4), 731-739 (2007-01-26)
The physical properties of polyaniline (PAn) powder, doped by nucleophilic doping of dimethyl sulfate (DMS), were characterized, as well as its electrochemical behaviors, to investigate the possibility of a power source device adopting the PAn-DMS electrodes. It is shown that
Cecilia E Ström et al.
Nucleic acids research, 39(8), 3166-3175 (2010-12-25)
Base excision repair (BER) represents the most important repair pathway of endogenous DNA lesions. Initially, a base damage is recognized, excised and a DNA single-strand break (SSB) intermediate forms. The SSB is then ligated, a process that employs proteins also
Yogo Sakakibara et al.
Journal of the American Chemical Society, 133(22), 8396-8399 (2011-05-12)
The movement of the small ribosomal subunit (30S) relative to the large ribosomal subunit (50S) during translation is widely known, but many molecular details and roles of rRNA and proteins in this process are still undefined, especially in solution models.
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