41640-M
二甲基亚砜
puriss. p.a., ACS reagent, ≥99.9% (GC)
别名:
DMSO, 甲基亚砜
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关于此项目
线性分子式:
(CH3)2SO
化学文摘社编号:
分子量:
78.13
UNSPSC Code:
12191502
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-664-3
Beilstein/REAXYS Number:
506008
MDL number:
Assay:
≥99.9% (GC)
Technique(s):
GC/GC: suitable
Bp:
189 °C (lit.)
Vapor pressure:
0.42 mmHg ( 20 °C)
vapor density
2.7 (vs air)
vapor pressure
0.42 mmHg ( 20 °C)
grade
ACS reagent, puriss. p.a.
assay
≥99.9% (GC)
form
liquid
autoignition temp.
573 °F
expl. lim.
42 %, 63 °F
technique(s)
GC/GC: suitable
impurities
≤0.001% free acid (as CH3COOH), ≤0.1% water
evapn. residue
≤0.005%
refractive index
n20/D 1.479
bp
189 °C (lit.)
mp
16-19 °C (lit.), 18-20 °C
density
1.10 g/mL (lit.)
cation traces
Al: ≤0.5 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.5 mg/kg, K: ≤0.5 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Mo: ≤0.1 mg/kg, Na: ≤1 mg/kg, Ni: ≤0.5 mg/kg, Pb: ≤0.1 mg/kg, Sr: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg
SMILES string
CS(C)=O
InChI
1S/C2H6OS/c1-4(2)3/h1-2H3
InChI key
IAZDPXIOMUYVGZ-UHFFFAOYSA-N
General description
Dimethyl sulfoxide (DMSO) is a polar solvent. DMSO activated by electrophile (oxalyl chloride) has been used to oxidize various alcohols (primary, secondary, allylic, benzylic, hindered and bicyclic). Carbonyl compounds are formed as reaction products. It has been proposed as an alternate solvent for methyl cellosolve for use in ninhydrin reaction, due to its high stability.
Application
- Ternary Phase-Field Simulation of Poly(vinylidene fluoride) Microporous Membrane Structures: Dimethyl sulfoxide (DMSO) is utilized in the formation of microporous membrane structures through phase separation techniques, enhancing polymer research for filtration and barrier applications (Zhang Z, et al., 2024).
- Application of copper (I) selective ligands for PET imaging: DMSO is employed in the synthesis of copper (I) selective ligands for positron emission tomography (PET) imaging, illustrating its role in advancing diagnostic techniques in medical research (Tada T, et al., 2024).
- Pillared graphene oxide frameworks for adsorption and separation: Research highlights the use of DMSO in exploring solvent interactions within graphene oxide frameworks, aiming to improve industrial processes for solvent recovery and environmental cleanup (Skarmoutsos I, et al., 2024).
- A Luminescent Hybrid Bimetallic Halide Family with Solvent-Coordinated Rare Earth and Alkaline Earth Metals: This study utilizes DMSO in the development of new luminescent materials, showcasing its importance in the creation of advanced materials for lighting and display technologies (Lin J, et al., 2024).
Other Notes
用于合成
For information on dimethyl sulfoxide miscibility, please visit the following link:
Dimethyl Sulfoxide Miscibility/Immiscibility Table
Dimethyl Sulfoxide Miscibility/Immiscibility Table
Disclaimer
在室温下容易过冷并缓慢重融。 固化产品可以通过加热至室温来重新液化，而不会损害产品。
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存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
188.6 °F - closed cup
flash_point_c
87 °C - closed cup
法规信息
新产品
此项目有
Birgit Dreier et al.
Methods in molecular biology (Clifton, N.J.), 805, 261-286 (2011-11-19)
Ribosome display has proven to be a powerful in vitro selection and evolution method for generating high-affinity binders from libraries of folded proteins. It has been successfully applied to single-chain Fv fragments of antibodies and alternative scaffolds, such as Designed
A RAPID PERMETHYLATION OF GLYCOLIPID, AND POLYSACCHARIDE CATALYZED BY METHYLSULFINYL CARBANION IN DIMETHYL SULFOXIDE.
S HAKOMORI
Journal of biochemistry, 55, 205-208 (1964-02-01)
Amino acid analysis: aqueous dimethyl sulfoxide as solvent for the ninhydrin reaction.
S Moore
The Journal of biological chemistry, 243(23), 6281-6283 (1968-12-10)