42743
(1S,2S)-(-)-1,2-二苯基乙二胺
purum, ≥97.0% (HPLC)
别名:
(1S,2S)-(-)-1,2-二氨基-1,2-二苯基乙烷
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关于此项目
线性分子式:
[C6H5CH(NH2)-]2
化学文摘社编号:
分子量:
212.29
PubChem Substance ID:
UNSPSC Code:
12352000
Beilstein/REAXYS Number:
3201645
MDL number:
grade
purum
assay
≥97.0% (HPLC)
optical activity
[α]20/D −105±3°, c = 1% in methanol
mp
79-83 °C, 83-85 °C (lit.)
storage temp.
2-8°C
SMILES string
N[C@H]([C@@H](N)c1ccccc1)c2ccccc2
InChI
1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m0/s1
InChI key
PONXTPCRRASWKW-KBPBESRZSA-N
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
V Larsimont et al.
Journal of pharmaceutical and biomedical analysis, 19(6), 855-864 (2000-03-04)
Two tyrosine specific, HPLC methods with either electrochemical (HPLC-ED) or fluorescence (HPLC-FL) detection are described for leucine-enkephalin (LE) in cerebrospinal fluid (CSF). Both approaches involve the hydroxylation of the Tyr1-moiety of LE by mushroom tyrosinase. Production of a catechol permitted
M Tellier et al.
Journal of pharmaceutical and biomedical analysis, 9(7), 557-563 (1991-01-01)
A new tyrosine-specific LC assay with pre-column fluorogenic derivatization is described for Tyr-Gly as model peptide. o-Hydroxylation of the tyrosine residue with tyrosinase in the presence of ascorbic acid, followed by oxidation to the corresponding quinone by potassium ferricyanide at
N M Maier et al.
Chirality, 8(7), 490-493 (1996-01-01)
Fast and efficient baseline separation of asymmetrically substituted diarylmethanols and 1,1-diarylethanols was achieved on an endcapped, amide-linked N-3,5-dinitrobenzoylated, (R,R)-1,2-diphenyl-1,2-ethanediamine-derived chiral stationary phase (CSP). Optimal enantioselectivities on this CSP were obtained using 1% 2-propanol in n-heptane as the mobile phase. Enantiorecognition
Michael L Berger et al.
Bioorganic & medicinal chemistry, 17(9), 3456-3462 (2009-04-07)
We resolved 1,2-diphenylethylamine (DPEA) into its (S)- and (R)-enantiomer and used them as precursors for synthesis of (S)- and (R)-1-(1,2-diphenylethyl)piperidine, flexible homeomorphs of the NMDA channel blocker MK-801. We also describe the synthesis of the dicyclohexyl analogues of DPEA. These
C Preston Pugh et al.
Archives of biochemistry and biophysics, 564, 244-253 (2014-12-03)
The widely used anticoagulant Coumadin (R/S-warfarin) undergoes oxidation by cytochromes P450 into hydroxywarfarins that subsequently become conjugated for excretion in urine. Hydroxywarfarins may modulate warfarin metabolism transcriptionally or through direct inhibition of cytochromes P450 and thus, UGT action toward hydroxywarfarin
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