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经验公式(希尔记法):
C16H14Cl2O4
化学文摘社编号:
分子量:
341.19
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
257-141-8
Beilstein/REAXYS Number:
2224754
MDL number:
InChI key
BACHBFVBHLGWSL-UHFFFAOYSA-N
InChI
1S/C16H14Cl2O4/c1-10(16(19)20-2)21-12-4-6-13(7-5-12)22-15-8-3-11(17)9-14(15)18/h3-10H,1-2H3
SMILES string
COC(=O)C(C)Oc1ccc(Oc2ccc(Cl)cc2Cl)cc1
grade
analytical standard
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
mp
42-48 °C (if solid)
application(s)
agriculture
environmental
format
neat
Quality Level
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General description
Diclofop-methyl is an early post-emergence phenoxypropanoic acid herbicide. Its mode of action involves inhibition of acetyl CoA carboxylase (ACCase) activity, which in turn decreases fatty acid synthesis in weeds and inhibits photosynthesis and the activity of meristem.
Application
Diclofop-methyl may be used as a reference standard for the determination of diclofop-methyl in soil samples by gas-liquid chromatography (GLC).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
农药列管产品
此项目有
Fatma Ünal et al.
Drug and chemical toxicology, 34(4), 390-395 (2011-07-01)
Diclofop-methyl (DM) is a chlorophenoxy derivative used in large quantities for the control of annual grasses in grain and vegetable crops. In this study, the genotoxic effects of DM were investigated by measuring chromosomal aberrations (CAs) in mouse bone-marrow cells
Qin Yu et al.
Planta, 230(4), 713-723 (2009-07-16)
This study investigates mechanisms of multiple resistance to glyphosate, acetyl-coenzyme A carboxylase (ACCase) and acetolactate synthase (ALS)-inhibiting herbicides in two Lolium rigidum populations from Australia. When treated with glyphosate, susceptible (S) plants accumulated 4- to 6-fold more shikimic acid than
Xiyun Cai et al.
Environmental toxicology and chemistry, 26(5), 970-975 (2007-05-25)
Information on the effects of pesticide degradation on aquatic organisms is needed to properly evaluate the ecotoxicity arising from the use of pesticides and for aquatic risk assessment. This work evaluated the toxicity of diclofop-methyl (DM) and its two major
Jose L De Prado et al.
Journal of agricultural and food chemistry, 53(6), 2185-2191 (2005-03-17)
Three diclofop-methyl (DM) resistant biotypes of Lolium rigidum (R1, R2, and R3) were found in different winter wheat fields in Spain, continuously treated with DM, DM + chlortoluron, or DM + isoproturon. Herbicide rates that inhibited shoot growth by 50%
Danuta Palut et al.
Roczniki Panstwowego Zakladu Higieny, 53(1), 1-9 (2002-06-11)
The study was designed to determine whether diclofop, introduced to environment as herbicide, would exert properties of chemical inducers of rat liver monooxygenase system related to CYP1A and CYP2B isozymes. For this purpose, the effect of diclofop on 7-etoxyresorufin O-dealkylase
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