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Merck
CN

49200

1,2,3,4,6-α-D-(+)-葡萄糖五乙酸酯

suitable for microbiology, ≥99.0% (sum of enantiomers, GC)

别名:

1,2,3,4,6-五-O-乙酰基-α-D-吡喃葡萄糖

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关于此项目

经验公式(希尔记法):
C16H22O11
化学文摘社编号:
分子量:
390.34
PubChem Substance ID:
UNSPSC Code:
12352200
EC Number:
210-073-2
MDL number:
Beilstein/REAXYS Number:
98852
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assay

≥99.0% (sum of enantiomers, GC)

optical activity

[α]20/D +100±2°, c = 5% in chloroform

mp

111-113 °C

solubility

chloroform: 0.1 g/mL, clear, colorless

application(s)

microbiology

SMILES string

CC(=O)OC[C@H]1O[C@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O

Other Notes

选择性 1-O-脱乙酰反应

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Skin Sens. 1A

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

涉药品监管产品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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J. Fiandor et al.
Synthesis, 1121-1121 (1985)
Tatiana Rodríguez-Pérez et al.
Nucleic acids symposium series (2004), (52)(52), 101-102 (2008-09-09)
An efficient synthesis protocol for the glucosyl-nucleoside phosphodiester derivatives has been developed. These mononucleotides were designed to act as pronucleotides with potential to deliver the parent compound as its monophosphate. Key step of the synthesis is the regioselective hydrolysis of
W J Malaisse
International journal of molecular medicine, 2(4), 383-388 (1998-12-19)
The two anomers of L-glucose pentaacetate were recently found to stimulate insulin release. The insulinotropic action of these esters cannot be attributed to the catabolism in islet cells of their glucidic or acetic moieties. The present review deals with an
Monosaccharide esters: clinically relevant?
E O Balasse
Acta clinica Belgica, 57(2), 47-48 (2002-08-03)
E Olivares et al.
Cell biochemistry and function, 16(4), 233-237 (1998-12-19)
The esterification of several monosaccharides, such as D-glucose, D-mannoheptulose and 2-deoxy-D-glucose was recently reported to increase their biological efficiency as either nutrient or antimetabolic agent. In the present study, however, the tetraacetate ester of streptozotocin was unexpectedly found to be

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