50070
甘氨酰胺 盐酸盐
≥99.0% (AT)
别名:
2-Aminoacetamide hydrochloride, Aminoacetamide hydrochloride, Glycine amide hydrochloride
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线性分子式:
NH2CH2CONH2 · HCl
化学文摘社编号:
分子量:
110.54
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-789-1
Beilstein/REAXYS Number:
3554199
MDL number:
Assay:
≥99.0% (AT)
Form:
solid
InChI key
WKNMKGVLOWGGOU-UHFFFAOYSA-N
InChI
1S/C2H6N2O.ClH/c3-1-2(4)5;/h1,3H2,(H2,4,5);1H
SMILES string
Cl.NCC(N)=O
assay
≥99.0% (AT)
form
solid
pKa (20 °C)
8.20
solubility
H2O: 0.1 g/mL, clear, colorless
anion traces
sulfate (SO42-): ≤50 mg/kg
cation traces
Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg
λ
0.5 M in H2O
UV absorption
λ: 260 nm Amax: 0.1
functional group
amide, amine
Quality Level
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Application
甘氨酰胺盐酸盐可用于合成[M（甘氨酰胺-N,N′）（ptpy）2]，其中ptpy = 2-(对甲苯基）吡啶酮），M=Rh或Ir。
它可用于合成以下甘氨酰胺基咪唑啉酮：
它可用于合成以下甘氨酰胺基咪唑啉酮：
- （±）-2-（2-苯丙基）咪唑烷-4-酮
- （±）-2-（2,4,4-三甲基戊基）咪唑烷-4-酮
- （±）-2-[（R）-2,6--二甲基-5-庚烯基]咪唑烷-4-酮
- （5R,6S,9R）-6-异丙基-9-甲基-1,4-二氮杂螺环[4.5]]癸烷-2-酮
- （5S,6S,9R）-6-异丙基-9-甲基-1,4-二氮杂螺环[4.5]]癸烷-2-酮
- （±）-2-甲基-2-戊基咪唑烷-4-酮
- （±）-2-乙基-2-（2-甲基丁基）咪唑啉-4-酮
- （±）-2-（-十一烷-2-基）咪唑烷-4-酮
- （±）-2-戊基咪唑烷-4-酮
- 2-（2,4-二甲基环己基-3-烯-1-基）咪唑烷-4-酮
Other Notes
用于肽偶联。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Preparation of Imidazolidin-4-ones and Their Evaluation as Hydrolytically Cleavable Precursors for the Slow Release of Bioactive Volatile Carbonyl Derivatives.
Trachsel A, et al.
European Journal of Organic Chemistry, 2012(14), 2837-2854 (2012)
N.J. Miles et al.
Journal of the Chemical Society. Perkin Transactions 1, 2299-2299 (1985)
Controlled gelation and sintering of monolithic gels prepared from g-alumina fume powder.
Tsai DS and Hsieh CC.
Journal of the American Ceramic Society. American Ceramic Society, 74(4), 830-836 (1991)
Synthesis and Characterization of New Bis-Cyclometalated Rhodium and Iridium Complexes Containing the Glycinamidato Ligand.
Graf M, et al.
Zeitschrift fur Anorganische und Allgemeine Chemie, 639(7), 1117-1121 (2013)
Irene M Lagoja et al.
Chemistry & biodiversity, 1(1), 106-111 (2006-12-29)
Because of their easy availability and their relative chemical stability, urea, formic acid, and glycine might have played a role in the assembly process of nucleobases. In this paper, a short reaction path is described to prepare hypoxanthine starting from
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