grade
puriss.
assay
≥99.0% (NT)
form
crystalline
optical activity
[α]20/D +42±2°, c = 2% in H2O
color
white
mp
~264 °C (dec.)
application(s)
peptide synthesis
SMILES string
NCC(=O)N[C@@H](Cc1ccccc1)C(O)=O
InChI
1S/C11H14N2O3/c12-7-10(14)13-9(11(15)16)6-8-4-2-1-3-5-8/h1-5,9H,6-7,12H2,(H,13,14)(H,15,16)/t9-/m0/s1
InChI key
JBCLFWXMTIKCCB-VIFPVBQESA-N
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
D J Porter et al.
The Journal of biological chemistry, 262(19), 9154-9159 (1987-07-05)
We identify the cyanogenic substrate for horseradish peroxidase (HRP) as a conjugated enamine and explore this unusual reaction using alpha-aminocinnamate (RH) as follows. 1) HRP catalyzes the oxidation of RH by O2 (and its peroxidation by H2O2 to form R-R)
Resolution of chiral compounds by HPLC using mobile phase additives and a porous graphitic carbon stationary phase.
B J Clark et al.
Journal of pharmaceutical and biomedical analysis, 7(12), 1883-1888 (1989-01-01)
J J Sperinde et al.
Bioconjugate chemistry, 10(2), 213-220 (1999-03-17)
Kinetic parameters have been measured for coupled nucleophilic and solvolytic reactions of 2,2,2-trifluoroethanesulfonyl (tresyl)-modified poly(ethylene glycol) based on a system of coupled differential equations implied by recently proposed elementary reaction mechanisms. Fitted kinetic parameters were found to be strong functions