InChI key
LDLDJEAVRNAEBW-SCSAIBSYSA-N
InChI
1S/C5H10O3/c1-4(6)3-5(7)8-2/h4,6H,3H2,1-2H3/t4-/m1/s1
SMILES string
COC(=O)C[C@@H](C)O
grade
puriss.
assay
≥99.0% (sum of enantiomers, GC)
optical activity
[α]20/D −50±2°, c = 1.3% in chloroform stab. with amylenes
optical purity
enantiomeric ratio: ≥98:2 (GC)
refractive index
n20/D 1.421 (lit.), n20/D 1.422
bp
56-58 °C/11 mmHg (lit.)
density
1.055 g/mL at 20 °C (lit.)
Other Notes
重要的光学活性化合物,用于制备各种双官能结构单元
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
First total synthesis of grahamimycin A.
Y Kobayashi et al.
The Journal of organic chemistry, 65(21), 7221-7224 (2000-10-14)
A new synthesis of a key intermediate of beta-lactam antibiotics via diastereoselective alkylation of beta-hydroxy ester.
W H Ham et al.
The Journal of organic chemistry, 65(24), 8372-8374 (2000-12-02)
A. Fischli et al.
Modern Synthetic Methods, 2, 269-269 (1980)
R M Garbaccio et al.
Organic letters, 2(20), 3127-3129 (2000-09-29)
A concise, stereospecific synthesis of radicicol dimethyl ether is presented. The strategy relies on a convergent three-stage assembly of the 14-membered lactone which has, as a key transformation, a novel ring-forming metathesis reaction utilizing a vinyl epoxide.
Xiao-Hong Chen et al.
PloS one, 9(4), e94543-e94543 (2014-04-18)
A novel carbonyl reductase (AcCR) catalyzing the asymmetric reduction of ketones to enantiopure alcohols with anti-Prelog stereoselectivity was found in Acetobacter sp. CCTCC M209061 and enriched 27.5-fold with an overall yield of 0.4% by purification. The enzyme showed a homotetrameric
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