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Merck
CN

55067

6-喹啉醇

technical, ≥95% (HPLC)

别名:

6-羟基喹啉

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经验公式(希尔记法):
C9H7NO
化学文摘社编号:
分子量:
145.16
EC Number:
209-454-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
113196
MDL number:
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grade

technical

assay

≥95% (HPLC)

mp

188-190 °C (lit.), 192-196 °C

SMILES string

Oc1ccc2ncccc2c1

InChI

1S/C9H7NO/c11-8-3-4-9-7(6-8)2-1-5-10-9/h1-6,11H

InChI key

OVYWMEWYEJLIER-UHFFFAOYSA-N

General description

6-Quinolinol can be prepared by refluxing a mixture of 6-methoxyquinoline bisulfate and concentrated hydrobromic acid followed by neutralization with ammonia.

Application

6-Quinolinol may be used in the preparation of the following heterocyclic compounds:
  • 1,2-dihydro-1-aryl[1,3]oxazino[5,6-f]quinolin-3-ones
  • highly substituted 4H-chromene derivatives
  • dioxino(5,4-f)quinoline
  • methyl 3-oxo-3H-pyrano[3,2-f]quinoline-1-carboxylate

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A clean synthesis of oxazino [5,6-f] quinolinone and naphtho [1,2-e] oxazinone derivatives.
Mosslemin MH, et al.
Monatshefte fur Chemie / Chemical Monthly, 139(10), 1247-1250 (2008)
A three-component, one-pot synthesis of oxazinoquinolin-3-one derivatives.
Shakibaei GI, et al.
Journal of Heterocyclic Chemistry, 45(5), 1481-1484 (2008)
Synthesis of novel pyridocoumarins and benzo-fused 6-azacoumarins.
Galariniotou E, et al.
Tetrahedron, 63(34), 8298-8304 (2007)
M S Mehata et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 59(3), 559-567 (2003-01-14)
Fluorescence characteristics of 6-hydroxyquinoline (6-HQ) have been studied at room temperature in Nafion(R) film by steady state and nano-second time-resolved fluorescence spectroscopy. The fluorescence spectrum exhibits single emission band corresponding to the protonated form of 6-HQ in this matrix. However
Mohan Singh Mehata
The journal of physical chemistry. B, 112(28), 8383-8386 (2008-06-20)
A hydrogen-bonded network formed between 6-hydroxyquinoline (6-HQ) and acetic acid (AcOH) has been characterized using a time-resolved fluorescence technique. In the bridged hydrogen-bonded complex of cis-6-HQ and AcOH, an excited-state reaction proceeds via proton transfer along the hydrogen bond, resulting

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货号GTIN
M104-25MG04061832091792
M104-5MG04061832091808

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