59446
2,3-异亚丙基-sn-甘油
purum, ≥97.0% (sum of enantiomers, GC)
别名:
(R)-(-)-2,2-二甲基-1,3-二氧戊环-4-甲醇, L-α,β-异亚丙基甘油
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关于此项目
经验公式（希尔记法）:
C6H12O3
化学文摘社编号:
分子量:
132.16
UNSPSC Code:
12352000
Beilstein/REAXYS Number:
80117
MDL number:
grade
purum
assay
≥97.0% (sum of enantiomers, GC)
optical activity
[α]/D −13.5±1°, neat
refractive index
n20/D 1.434
bp
75-78 °C/12 mmHg
density
1.064 g/mL at 20 °C (lit.)
storage temp.
2-8°C
SMILES string
CC1(C)OC[C@@H](CO)O1
InChI
1S/C6H12O3/c1-6(2)8-4-5(3-7)9-6/h5,7H,3-4H2,1-2H3/t5-/m1/s1
InChI key
RNVYQYLELCKWAN-RXMQYKEDSA-N
Other Notes
合成 GABOB、甘油酯和很多其他化合物的关键中间体；也可参阅 59445 D-对映体
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
M.E. Jung et al.
Journal of the American Chemical Society, 102, 6304-6304 (1980)
Changning Guo et al.
Chirality, 18(10), 775-782 (2006-08-15)
Near-infrared (near-IR) Fourier transform vibrational circular dichroism (FT-VCD) spectroscopy has been used to monitor the epimerization of (S)-(+)-2,2-dimethyl-1,3-dioxolane-4-methanol (S-DDM). The near-IR-VCD spectra display clear isolated VCD bands at the range of 4700-5050 cm(-1) resulting from the OH stretch-bend combination bands
P Kanda et al.
Journal of lipid research, 22(5), 879-882 (1981-07-01)
The preparation of sn-glycero-1-phosphocholine is described. 2,3-O-Isopropylidene-sn-glycerol is condensed first with the 1,2-dimethylethenylene phosphorochloridate in the presence of triethylamine to yield the cyclic phosphotriester derivative. Choline p-toluenesulfonate, as the second alcohol, is condensed with this intermediate to yield the phosphotriester
[Interference of the action of dimethyl-2,2-hydroxymethyl-4 dioxolane- 1,3 (AG) with various active pharmacomolecules on the central nervous system].
S L Cheav et al.
Annales pharmaceutiques francaises, 45(6), 445-451 (1987-01-01)
Xiaolin Cao et al.
Applied spectroscopy, 58(9), 1057-1064 (2004-10-14)
We report the first vibrational circular dichroism (VCD) spectra with continuous coverage from 800 cm(-1) in the mid-infrared (MIR) region to 10 000 cm(-1) in the near-infrared (NIR) region. This coverage is illustrated with MIR and NIR absorbance and VCD
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