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Merck
CN

63940

4-甲基-3-戊烯-2-酮

technical, ≥90% (GC)

别名:

米基化氧

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关于此项目

线性分子式:
(CH3)2C=CHCOCH3
化学文摘社编号:
分子量:
98.14
EC Number:
205-502-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1361550
MDL number:
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InChI key

SHOJXDKTYKFBRD-UHFFFAOYSA-N

InChI

1S/C6H10O/c1-5(2)4-6(3)7/h4H,1-3H3

SMILES string

C\C(C)=C\C(C)=O

grade

technical

assay

≥90% (GC)

refractive index

n20/D 1.442 (lit.), n20/D 1.45

bp

130 °C (lit.)

mp

-41.5 °C (lit.)

density

0.858 g/mL at 25 °C (lit.)

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General description

Mesityl oxide can be synthesized by acetone–n-butanol–ethanol(ABE) fermentation of ligno-cellulose.

Application

Mesityl oxide can be used in the synthesis of diesel range alkanes via alkylation with 2-methylfuran in the presence of solid acid catalysts. It can also be used to synthesize methyl isobutyl ketone(MIBK), which has a wide range of applications as a solvent in inks and lacquers.

pictograms

FlameSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

87.8 °F - closed cup

flash_point_c

31 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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"One-step MIBK synthesis: a new process from 2-propanol?
Cosimo D.I.J, et al.
J. Catal., 208(01), 114-123 (2002)
"Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose"
Li S, et al.
Catalysis Today, 234, 91-99 (2014)
Christian Starkenmann
Journal of agricultural and food chemistry, 51(24), 7146-7155 (2003-11-13)
Cysteine conjugates, resulting from the addition of cysteine to alpha,beta-unsaturated carbonyl compounds, are important precursors of odorant sulfur compounds in food flavors. The aim of this work was to better understand this chemistry in the light of the unexpected double
Z Jia et al.
Electrophoresis, 22(6), 1112-1118 (2001-05-19)
A fast screening method for the determination of the dissociation constants (pKa) of acidic, basic, and multivalent compounds was developed by using pressure-assisted capillary electrophoresis (PACE). External air pressure was applied to shorten the analysis time. The separation efficiency decreases
Scott E Denmark et al.
The Journal of organic chemistry, 71(4), 1668-1676 (2006-02-14)
The mechanism of the formation of substituted quinolines from anilines and alpha,beta-unsaturated ketones has been studied by the use of 13C-labeled ketones in cross-over experiments. In the reaction of doubly labeled 13C(2,4) mesityl oxide, a 100% scrambling of the label

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