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Merck
CN

69692

3-丁烯-2-酮

purum, ≥95.0% (GC)

别名:

丁烯酮, 甲基乙烯基酮

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线性分子式:
CH2=CHCOCH3
化学文摘社编号:
分子量:
70.09
EC Number:
201-160-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
506021
MDL number:
Assay:
≥95.0% (GC)
Form:
liquid
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InChI key

FUSUHKVFWTUUBE-UHFFFAOYSA-N

InChI

1S/C4H6O/c1-3-4(2)5/h3H,1H2,2H3

SMILES string

CC(=O)C=C

vapor density

1.3 (vs air)

vapor pressure

310 mmHg ( 55 °C), 71 mmHg ( 20 °C)

grade

purum

assay

≥95.0% (GC)

form

liquid

contains

~0.5% acetic acid as stabilizer, ~0.5% hydroquinone as stabilizer

expl. lim.

15.64 %

impurities

~5% water

Quality Level

refractive index

n20/D 1.412

bp

81 °C (lit.)

density

0.86 g/mL at 20 °C, 0.864 g/mL at 25 °C (lit.)

storage temp.

2-8°C

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Disclaimer

储存时可变为褐色

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

19.4 °F - closed cup

flash_point_c

-7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Kavita De et al.
The Journal of organic chemistry, 74(16), 6260-6265 (2009-07-23)
1,4-Addition of anilines onto Michael acceptors proceeds easily in specific polar protic solvents, without any promoting agent. According to the solvent and to the electrophile, the selectivity of the reaction can be finely tuned. With methyl acrylate as electrophile, only
Laura L Thomas et al.
Journal of the American Chemical Society, 132(9), 3097-3104 (2010-02-13)
Quantum and molecular mechanics calculations for the Diels-Alder reactions of cyclopentadiene with 1,4-naphthoquinone, methyl vinyl ketone, and acrylonitrile have been carried out at the vacuum-water interface and in the gas phase. In conjunction with previous studies of these cycloadditions in
Palladium-mediated annulation of vinyl aziridines with Michael acceptors: stereocontrolled synthesis of substituted pyrrolidines and its application in a formal synthesis of (-)-α-kainic acid.
Martin A Lowe et al.
Angewandte Chemie (International ed. in English), 50(28), 6370-6374 (2011-06-01)
Yonggui Chi et al.
Journal of the American Chemical Society, 130(20), 6322-6323 (2008-04-25)
Non-interpenetrating star polymer catalysts designed to mimic the site isolation characteristics of enzymes enable the one-pot combination of multiple otherwise incompatible catalysts for asymmetric cascade reactions that involve iminium, enamine, and H-bonding catalysis. Control experiments replacing star polymer catalysts with
Hans von Stedingk et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 878(27), 2491-2496 (2010-04-20)
Adducts to N-terminal valines in Hb have been shown useful as biomarkers of exposure to electrophilic compounds. Adducts from many compounds have earlier been measured with a modified Edman degradation method using a GC-MS/MS method. A recently developed method, the

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