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Merck
CN

71330

溴化钠

purum p.a., ≥99.0% (AT)

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关于此项目

线性分子式:
NaBr
化学文摘社编号:
分子量:
102.89
EC Number:
231-599-9
UNSPSC Code:
12352300
MDL number:
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vapor pressure

1 mmHg ( 806 °C)

grade

purum p.a.

assay

≥99.0% (AT)

mp

755 °C (lit.)

solubility

ethanol: soluble(lit.), water: soluble(lit.)

anion traces

chloride (Cl-): ≤1000 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Cu: ≤50 mg/kg, Fe: ≤50 mg/kg, K: ≤2000 mg/kg, Ni: ≤50 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg

SMILES string

[Na+].[Br-]

InChI

1S/BrH.Na/h1H;/q;+1/p-1

InChI key

JHJLBTNAGRQEKS-UHFFFAOYSA-M

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General description

Sodium bromide, an alkaline-earth chloride, is an inorganic salt. It has been synthesized by reacting soda with iron(II,III)bromide.

Application

Sodium bromide may be used in the following studies:
  • As a catalyst for the microwave assisted three-component cyclocondensation of aryl aldehydes, alkyl nitriles and dimedone for the synthesis of highly functionalized tetrahydrobenzo[b]pyrans.
  • To compose the aqueous two-phase system (ATPS).
  • Preparation of unoxidized and carboxylated pullulan, which are employed as mediators during the preparation of silver nanoparticles (AgNPs).

Other Notes

用于在酶催化反应中还原中间体(例如硫酯、席夫碱和磷酸酯中间体)

pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Repr. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

存储类别

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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分析证书(COA)

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The chemical structure of tryptophanase from Escherichia coli. I. Isolation and structure of a pyridoxyl decapeptide from borohydride-reduced holotryptophanase.
H Kagamiyama et al.
The Journal of biological chemistry, 245(11), 2819-2824 (1970-06-10)
J A Todhunter et al.
The Journal of biological chemistry, 250(9), 3505-3509 (1975-05-10)
Incubation of unadenylylated Escherichia coli glutamine synthetase with ATP, L-[14C]glutamate and metal ion results in the formation of gamma-glutamyl-P which can under appropriate conditions be reduced by sodium borohydride. The acyl-P compound is formed catalytically as judged by the quantity
Sodium bromide catalysed one-pot synthesis of tetrahydrobenzo [b] pyrans via a three-component cyclocondensation under microwave irradiation and solvent free conditions.
Devi I and Bhuyan PJ.
Tetrahedron Letters, 45(47), 8625-8627 (2004)
Eagleson M.
Concise Encyclopedia Chemistry, 996-996 (1994)
Ling Yue et al.
Applied biochemistry and biotechnology, 175(7), 3557-3570 (2015-02-05)
A novel aqueous two-phase system (ATPS) only containing Gemini surfactant ethanediyl-1,2-bis(dodecyldimethylammonium bromide) and an inorganic salt sodium bromide was designed, and the physicochemical properties of the ATPS were investigated systematically. The results have shown that the coexisting two phases, one

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