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Merck
CN

71495

Red-Al® 双(2-甲氧乙氧基)氢化铝钠 溶液

technical, ~70% in toluene (~3.5 M)

别名:

SBAH, 二氢双(2-甲氧乙氧基)铝酸钠

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关于此项目

线性分子式:
NaAlH2(OCH2CH2OCH3)2
化学文摘社编号:
分子量:
202.16
UNSPSC Code:
12352000
PubChem Substance ID:
MDL number:
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grade

technical

expl. lim.

7 %

reaction suitability

reagent type: reductant

concentration

~70% in toluene (~3.5 M)

density

1.02 g/mL at 20 °C

SMILES string

[Na+].[H][Al-]([H])(OCCOC)OCCOC

InChI

1S/2C3H7O2.Al.Na.2H/c2*1-5-3-2-4;;;;/h2*2-3H2,1H3;;;;/q2*-1;2*+1;;

InChI key

XJIQVZMZXHEYOY-UHFFFAOYSA-N

Other Notes

综述

Legal Information

Red-Al is a registered trademark of Merck KGaA, Darmstadt, Germany


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O. Strouf et al.
Sodium dihydrido-bis(2-methoxyethoxo)aluminate, J. Organomet. Chem. Library, 15 null
L E Pope et al.
Journal of lipid research, 37(10), 2167-2178 (1996-10-01)
The 22-carbon fatty alcohol, n-docosanol, exhibits in vitro antiviral activity against several lipid-enveloped viruses including herpes simplex viruses 1 and 2 by a mechanism that interferes with normal viral entry into target cells. We previously reported that mammalian cells incorporate
Naval Bajwa et al.
The Journal of organic chemistry, 73(9), 3638-3641 (2008-03-25)
In this paper, we have demonstrated that Red-Al is an efficient chelation-controlled reducing reagent for acyclic acetal (i.e., MOM, MEM, SEM, and BOM) protected alpha-hydroxy ketones. Typically, diastereomeric ratios (dr) ranged from 5 to 20:1 for the 1,2- anti-diols in