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Merck
CN

72491

茚三酮

≥95.0% (UV)

别名:

2,2-二羟基-1,3-茚二酮, 苯并戊三酮 一水合物, 苯并环丙三酮 一水合物

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关于此项目

经验公式(希尔记法):
C9H6O4
化学文摘社编号:
分子量:
178.14
EC Number:
207-618-1
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1910963
MDL number:
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assay

≥95.0% (UV)

form

crystals

mp

250 °C (dec.) (lit.)

SMILES string

OC1(O)C(=O)c2ccccc2C1=O

InChI

1S/C9H6O4/c10-7-5-3-1-2-4-6(5)8(11)9(7,12)13/h1-4,12-13H

InChI key

FEMOMIGRRWSMCU-UHFFFAOYSA-N

General description

Ninhydrin, a tricyclic 1,2,3-trione, is a useful organic building block.

Application

Ninhydrin (Triketohydrindene hydrate) may be used as a reagent for the quantification of amino acids and peptides by photometric method and colorimetric method. It may be used to prepare the ninhydrin reagent, by mixing ninhydrin and hydrindantin (reduced form of ninhydrin) in dimethyl sulfoxide. This reagent is used in manual ninhydrin method for the quantitative determination of amino acids.
可以用于检测氨基酸,多肽和蛋白质中的自由氨基基团。


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signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Isomerization of Ninhydrin-Heterocyclic Ketene Aminal Adducts: Kinetic versus Thermodynamic Control, Solvent Dependency and Mechanism.
Chen N, et al.
European Journal of Organic Chemistry, 28, 6210-6218 (2014)
Photometric ninhydrin method for use in the chromatography of amino acids.
S MOORE et al.
The Journal of biological chemistry, 176(1), 367-388 (1948-10-01)
Ninhydrin as a building block in scaffold-linked chromophoric dyad construction.
Margetic D, et al.
ARKIVOC (Gainesville, FL, United States), 210, 224-224 (2014)