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Merck
CN

73325

硝基乙酸甲酯

purum, ≥97.0% (GC)

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线性分子式:
NO2CH2COOCH3
化学文摘社编号:
分子量:
119.08
EC Number:
219-622-0
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
1758670
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grade

purum

assay

≥97.0% (GC)

refractive index

n20/D 1.425 (lit.), n20/D 1.426

bp

195-198 °C (lit.)

density

1.294 g/mL at 25 °C (lit.)

SMILES string

COC(=O)C[N+]([O-])=O

InChI

1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3

InChI key

ALBSWLMUHHZLLR-UHFFFAOYSA-N

Other Notes

用于有机合成,综述;由烯酮合成 2,5-二氧链烷酸酯

Disclaimer

储存时可能变为黄色

法规信息

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M.T. Shipchandler
Synthesis, 666-666 (1979)
W.J. Thompson et al.
The Journal of Organic Chemistry, 48, 2769-2769 (1983)
Benoît Moreau et al.
Journal of the American Chemical Society, 127(51), 18014-18015 (2005-12-22)
A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and methyl nitroacetate is reported. The cyclopropanation took place with high enantioselectivity for a wide range
[Experimental establishment of the maximum permissible concentration of the methyl and ethyl esters of nitroacetic acid].
G I Sidorin et al.
Gigiena truda i professional'nye zabolevaniia, (7)(7), 49-51 (1980-07-01)

全球贸易项目编号

货号GTIN
4160-100GM04055977187779
105357901004022536906904
105362010004022536063539
816008002504022536423500
816008001004022536423494
W527602-100G04061835567713
PHR1099-1G04061835237319
I5281-25KG04061834432388
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I7403-1KG04061826756393
I046000004061833811856
I2752-100G04061835361373
I2752-25G04061835361410
1349502-200MG04061838730374
105362002504022536063522
105357100004022536906898
105362901004022536692739
105362050004022536063546
56241-1G04061834232896

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