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73478

硝基甲烷

Name: 硝基甲烷
Brand: SIAL

puriss., absolute, over molecular sieve, ≥98.5% (GC)

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关于此项目

经验公式（希尔记法）:

CH₃NO₂

化学文摘社编号:

75-52-5

分子量:

61.04

UNSPSC Code:

12352102

NACRES:

NA.21

PubChem Substance ID:

57652479

EC Number:

200-876-6

Beilstein/REAXYS Number:

1698205

MDL number:

MFCD00007400

Assay:

≥98.5% (GC)

Technique(s):

GC/GC: suitable

Bp:

101.2 °C (lit.)

Vapor pressure:

2.7 mmHg

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属性

vapor density

2.1 (vs air)

Quality Level

100

vapor pressure

2.7 mmHg

grade

absolute, puriss.

assay

≥98.5% (GC)

form

liquid

autoignition temp.

784 °F

quality

over molecular sieve

expl. lim.

7.3 %, 33 °F

technique(s)

GC/GC: suitable

impurities

≤0.01% water
water

refractive index

n20/D 1.382

pH

6.4 (20 °C, 0.01 g/L)

bp

101.2 °C (lit.)

mp

−29 °C (lit.)

density

1.127 g/mL at 25 °C (lit.)

SMILES string

C[N+]([O-])=O

InChI

1S/CH3NO2/c1-2(3)4/h1H3

InChI key

LYGJENNIWJXYER-UHFFFAOYSA-N

说明

General description

硝基甲烷是一种脂肪族硝基化合物。在金鸡纳生物碱衍生的手性双功能硫脲有机催化剂存在下，它与查耳酮发生 Michael 加成反应。研究了在 Co-ZSM5（沸石 Socony Mobil-5）存在下，其向 N ₂ 的转化。

Application

硝基甲烷可用于制备钴笼络合物。

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pictograms

GHS02,GHS08,GHS07

signalword

Warning

hcodes

H226,H302 + H332,H351,H361d

pcodes

P202 - P210 - P233 - P301 + P312 - P304 + P340 + P312 - P308 + P313

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2

存储类别

4.1A - Other explosive hazardous materials

wgk

WGK 2

flash_point_f

95.0 °F - closed cup

flash_point_c

35 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

易制爆化学品

危险化学品

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Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.

Geue RJ, et al.

Journal of the American Chemical Society, 106(19), 5478-5488 (1984)

The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NO_xSCR reaction.

Cowan AD, et al.

J. Catal., 176(2), 329-343 (1998)

Synthesis of chemical tools to improve water solubility and promote the delivery of salinomycin to cancer cells.

Loay Awad

Experimental and therapeutic medicine, 19(3), 1835-1843 (2020-02-28)

Chemotherapy and radiation are unable to eliminate all cancer cells, particularly apoptosis-resistant cancer cells, despite their ability to kill cancer cluster cells. Thus, it is important to identify methods that eliminate all cancer cells in order to prevent relapse. Salinomycin

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货号	GTIN
73478-100ML	04061832868493
73478-500ML	04061837535109