74520
降樟脑
purum, ≥98.0% (GC)
别名:
2-降冰片醇, 双环[2.2.1]庚-2-酮
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关于此项目
经验公式（希尔记法）:
C7H10O
化学文摘社编号:
分子量:
110.15
EC Number:
207-846-1
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1209657
MDL number:
grade
purum
assay
≥98.0% (GC)
bp
168-172 °C (lit.)
mp
91-96 °C, 93-96 °C (lit.)
SMILES string
O=C1C[C@@H]2CC[C@H]1C2
InChI
1S/C7H10O/c8-7-4-5-1-2-6(7)3-5/h5-6H,1-4H2/t5-,6+/m1/s1
InChI key
KPMKEVXVVHNIEY-RITPCOANSA-N
W M Atkins et al.
Biochemistry, 27(5), 1610-1616 (1988-03-08)
The kinetics of NADH consumption, oxygen uptake, and hydrogen peroxide production have been studied for norcamphor metabolism by cytochrome P-450cam. The kinetic deuterium isotope effects on these processes, with specifically deuteriated norcamphor, are 0.77, 1.22, and 1.16, respectively. Steady-state UV-visible
Sarasij Kumar Upadhyay et al.
The Journal of organic chemistry, 76(5), 1355-1360 (2011-01-22)
The endo/exo product ratio in the reactions of SmI(2) with norcamphor in the presence of various proton donors was determined. The effect of MeOH, EtOH, trifluoroethanol (TFE), ethylene glycol (EG), and water was investigated at various concentrations of these proton
Lars Goerigk et al.
The journal of physical chemistry. A, 113(4), 767-776 (2008-12-24)
Time-dependent double-hybrid density functional theory is applied to the calculation of the electronic circular dichroism (CD) spectra of molecules. The TD-B2PLYP method is based on vertical excitation energies obtained from its hybrid-GGA part B2LYP in a conventional TD-DFT linear response
M B Bass et al.
Proteins, 13(1), 26-37 (1992-05-01)
While cytochrome P-450cam catalyzes the hydroxylation of camphor to 5-exo-hydroxycamphor with 100% stereospecificity, norcamphor is hydroxylated by this enzyme yielding 45% 5-exo-, 47% 6-exo-, and 8% 3-exo-hydroxynorcamphor (Atkins, W.M., Sligar, S.G., J. Am. Chem. Soc. 109:3754-3760, 1987). The present study
J R Collins et al.
The Journal of biological chemistry, 263(7), 3164-3170 (1988-03-05)
The hydroxylations of d-camphor, norcamphor, pericyclocamphanone, and 5,5-difluorocamphor by cytochrome P-450cam have been examined using theoretical methods to identify and characterize properties which determine product specificity. Experimental results indicate that each molecule is hydroxylated with quite different regio-specificity when metabolized
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