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Merck
CN

75018

1-己硫醇

analytical standard

别名:

1-巯基己烷, Hexyl mercaptan, MCH, Mercaptan C6

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关于此项目

线性分子式:
CH3(CH2)5SH
化学文摘社编号:
分子量:
118.24
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
EC Number:
203-857-0
Beilstein/REAXYS Number:
1731295
MDL number:
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InChI key

PMBXCGGQNSVESQ-UHFFFAOYSA-N

InChI

1S/C6H14S/c1-2-3-4-5-6-7/h7H,2-6H2,1H3

SMILES string

CCCCCCS

grade

analytical standard

assay

≥98.0% (GC)

shelf life

limited shelf life, expiry date on the label

refractive index

n20/D 1.448-1.452, n20/D 1.450

bp

150-154 °C (lit.)

mp

−81-−80 °C (lit.)

density

0.832 g/mL at 25 °C

application(s)

cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care

format

neat

Quality Level

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General description

1-Hexanethiol is an organic sulfur compound that belongs to the class of mercaptans. Mercaptans have a characteristic odor and are regarded as the major contributors to several foods and beverage aromas.

Application

1-Hexanethiol may be used as a surrogate standard for the determination of wine polyfunctional mercaptans by gas chromatography−negative ion mass spectrometry analysis of their pentafluorobenzyl derivatives. It may also be used as an analytical standard for the determination of the analyte in alcoholic beverages by simultaneous derivatization/extraction and liquid chromatography-high resolution mass spectrometry.

pictograms

FlameExclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

86.0 °F - closed cup

flash_point_c

30 °C - closed cup

法规信息

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分析证书(COA)

Lot/Batch Number

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Analysis of volatile thiols in alcoholic beverages by simultaneous derivatization/extraction and liquid chromatography-high resolution mass spectrometry
Vichi S, et al.
Food Chemistry, 175(2), 401-408 (2015)
Anupama Tyagi et al.
Prostaglandins, leukotrienes, and essential fatty acids, 91(6), 289-297 (2014-12-03)
Imbalances in the dietary n-6 and n-3 polyunsaturated fatty acids have been implicated in the increased prevalence of inflammatory bowel disease. This study investigated the effects of substitution of linoleic acid with long chain n-3 polyunsaturated fatty acids and hence
Laura Mateo-Vivaracho et al.
Journal of chromatography. A, 1146(2), 242-250 (2007-02-24)
A fast method for the determination of aroma-powerful polyfunctional thiols at nanogram per liter level has been developed and applied to wine. A small volume of wine (6 mL) was extracted with 1.5 mL of benzene containing four internal standards.
Hao Chen et al.
PloS one, 10(2), e0115482-e0115482 (2015-02-07)
Giant cell arteritis (GCA) and Takayasu's disease are inflammatory vasculitic syndromes (IVS) causing sudden blindness and widespread arterial obstruction and aneurysm formation. Glucocorticoids and aspirin are mainstays of treatment, predominantly targeting T cells. Serp-1, a Myxomavirus-derived serpin, blocks macrophage and
Chang Liu et al.
The Analyst, 139(21), 5460-5465 (2014-08-30)
Due to its low growth rate and its fastidious nature, Mycobacterium tuberculosis is difficult to identify. Its rapid and sensitive detection is, however, critical for the control of tuberculosis. Molecular biology, and more recently electrochemical technology, have been exploited for

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