76466
(-)-鹰爪豆碱
≥98.0% (GC)
别名:
(-)-司巴丁
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关于此项目
经验公式（希尔记法）:
C15H26N2
化学文摘社编号:
分子量:
234.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
23151817
EC Number:
201-988-8
MDL number:
InChI key
SLRCCWJSBJZJBV-ZQDZILKHSA-N
InChI
1S/C15H26N2/c1-3-7-16-11-13-9-12(14(16)5-1)10-17-8-4-2-6-15(13)17/h12-15H,1-11H2/t12-,13-,14-,15+/m0/s1
SMILES string
C1CCN2C[C@@H]3C[C@@H](CN4CCCC[C@H]34)[C@@H]2C1
assay
≥98.0% (GC)
form
liquid
optical activity
[α]/D -17.5±1.5°, c = 1 in ethanol
refractive index
n20/D 1.526-1.530, n20/D 1.528 (lit.)
bp
137-138 °C/1 mmHg (lit.)
density
1.02 g/mL at 25 °C (lit.)
Quality Level
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General description
Sparteine belongs to lupin alkaloid class of compounds. It is a well-known neurological toxin.
Application
(−)-Sparteine may be used as a chiral diamino ligand in the asymmetric catalysis reactions involving alkyllithium bases. It may be used as a reference standard for the determination of (−)-sparteine in animal-derived food products by modified quick, easy, cheap, effective, rugged, and safe (CEN QuEChERS) extraction method followed by analysis using liquid chromatography-electrospray ionization tandem mass spectrometry (LC-ESI/MS-MS).
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
法规信息
新产品
此项目有
Diurnal cycle of sparteine production in Lupinus arcticus.
Sharam GJ and Turkington R
Canadian Journal of Botany. Journal Canadien De Botanique, 83(10), 1345-1348 (2005)
A modified QuEChERS method coupled with liquid chromatography-tandem mass spectrometry for the simultaneous detection and quantification of scopolamine, L-hyoscyamine, and sparteine residues in animal-derived food products.
Zheng W, et al.
Journal of Advanced Research (2018)
New chiral diamino ligands as sparteine analogues. Application to the palladium-catalyzed kinetic oxidative resolution of 1-phenyl ethanol.
Lesma G, et al.
Tetrahedron Asymmetry, 19(11), 1363-1366 (2008)
Microwave-assisted extraction of tanshinones from Salvia miltiorrhiza bunge with analysis by high-performance liquid chromatography.
Pan X, et al.
Journal of Chromatography A, 922(1-2), 371-375 (2001)
Synthesis of enantiomerically pure 2,2'-dihydroxy-1,1'-binaphthyl, 2,2'-diamino-1,1'-binaphthyl, and 2-amino-2'-hydroxy-1,1'-binaphthyl. Comparison of processes operating as diastereoselective crystallization and as second order asymmetric transformation.
Smrcina, M,. et al.
The Journal of Organic Chemistry, 57, 1917-1920 (1992)
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