77460
2-Chloroacetophenone
purum, ≥98.0% (GC)
别名:
ω-Chloroacetophenone, Phenacyl chloride
等级
purum
质量水平
方案
≥98.0% (GC)
表单
crystals
沸点
244-245 °C (lit.)
mp
53-56 °C
54-56 °C (lit.)
密度
1.324 g/mL at 25 °C (lit.)
官能团
chloro
ketone
phenyl
SMILES字符串
ClCC(=O)c1ccccc1
InChI
1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2
InChI key
IMACFCSSMIZSPP-UHFFFAOYSA-N
基因信息
human ... PTPN6(5777)
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一般描述
2-Chloroacetophenone is an organic building block used in the synthesis of heterocyclic compounds. It has low solubility in water but can be soluble in alcohols, ethers and other organic solvents.
应用
2-Chloroacetophenone can be used in the synthesis of phenyl acetic acid by Photo-Favorskii rearrangement. It is also used in the preparation of 1-(2-chlorophenyl)ethanol via asymmetric hydrogenation reaction.
警示用语：
Danger
危险分类
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Preparation of microgel-supported chiral catalysts and their application in the asymmetric hydrogenation of aromatic ketones
Deng J, et al.
Reactive and Functional Polymers, 72, 378-382 (2012)
Experimental study of the adsorption of 2-Chloroacetophenone at the air-environmental water interface
Hao, et al.
Frontiers in environmental science., 10, 2254-2254 (2022)
Principles of coaxial illumination for photochemical reactions: Part 2. Model validation
Meir, et al.
Journal of advanced materials and processing, 2 (2020)
Ionic liquid mediated and promoted one-pot green synthesis of new isoxazolyl dihydro-1 H-indol-4 (5 H)-one derivatives at ambient temperature
Modugu, et al.
Cogent Chemistry , 3, 1318693-1318693 (2017)
Expanding the [1,2]-aryl migration to the synthesis of substituted indoles.
Tao Pei et al.
Angewandte Chemie (International ed. in English), 47(22), 4231-4233 (2008-04-30)
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