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77460

2-Chloroacetophenone

Name: 2-Chloroacetophenone
Brand: SIAL

purum, ≥98.0% (GC)

别名:

ω-Chloroacetophenone, Phenacyl chloride

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关于此项目

线性分子式:

C₆H₅COCH₂Cl

化学文摘社编号:

532-27-4

分子量:

154.59

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

329767699

EC Number:

208-531-1

Beilstein/REAXYS Number:

507950

MDL number:

MFCD00000933

Assay:

≥98.0% (GC)

Form:

crystals

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属性

grade

purum

Quality Level

200

assay

≥98.0% (GC)

form

crystals

bp

244-245 °C (lit.)

mp

53-56 °C, 54-56 °C (lit.)

density

1.324 g/mL at 25 °C (lit.)

functional group

chloro, ketone, phenyl

SMILES string

ClCC(=O)c1ccccc1

InChI

1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

InChI key

IMACFCSSMIZSPP-UHFFFAOYSA-N

Gene Information

human ... PTPN6(5777)

说明

General description

2-Chloroacetophenone is an organic building block used in the synthesis of heterocyclic compounds. It has low solubility in water but can be soluble in alcohols, ethers and other organic solvents.

Application

2-Chloroacetophenone can be used in the synthesis of phenyl acetic acid by Photo-Favorskii rearrangement. It is also used in the preparation of 1-(2-chlorophenyl)ethanol via asymmetric hydrogenation reaction.

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pictograms

GHS06,GHS08,GHS05

signalword

Danger

hcodes

H300,H311 + H331,H315,H318,H334,H335

pcodes

P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Experimental study of the adsorption of 2-Chloroacetophenone at the air-environmental water interface

Hao, et al.

Frontiers in environmental science., 10, 2254-2254 (2022)

Preparation of microgel-supported chiral catalysts and their application in the asymmetric hydrogenation of aromatic ketones

Deng J, et al.

Reactive and Functional Polymers, 72, 378-382 (2012)

Principles of coaxial illumination for photochemical reactions: Part 2. Model validation

Meir, et al.

Journal of advanced materials and processing, 2 (2020)

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全球贸易项目编号

货号	GTIN
77460-100G	04061836686741
77460-500G	04061836686758