77460
2-Chloroacetophenone
purum, ≥98.0% (GC)
别名:
ω-Chloroacetophenone, Phenacyl chloride
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关于此项目
线性分子式:
C6H5COCH2Cl
化学文摘社编号:
分子量:
154.59
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-531-1
Beilstein/REAXYS Number:
507950
MDL number:
Assay:
≥98.0% (GC)
Form:
crystals
InChI key
IMACFCSSMIZSPP-UHFFFAOYSA-N
InChI
1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2
SMILES string
ClCC(=O)c1ccccc1
grade
purum
assay
≥98.0% (GC)
form
crystals
bp
244-245 °C (lit.)
mp
53-56 °C
Quality Level
Gene Information
human ... PTPN6(5777)
density
1.324 g/mL at 25 °C (lit.)
functional group
chloro, ketone, phenyl
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General description
2-Chloroacetophenone is an organic building block used in the synthesis of heterocyclic compounds. It has low solubility in water but can be soluble in alcohols, ethers and other organic solvents.
Application
2-Chloroacetophenone can be used in the synthesis of phenyl acetic acid by Photo-Favorskii rearrangement. It is also used in the preparation of 1-(2-chlorophenyl)ethanol via asymmetric hydrogenation reaction.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Preparation of microgel-supported chiral catalysts and their application in the asymmetric hydrogenation of aromatic ketones
Deng J, et al.
Reactive and Functional Polymers, 72, 378-382 (2012)
Experimental study of the adsorption of 2-Chloroacetophenone at the air-environmental water interface
Hao, et al.
Frontiers in environmental science., 10, 2254-2254 (2022)
Anil K Nigam et al.
Journal of hazardous materials, 184(1-3), 506-514 (2010-09-17)
Pyrolysis-GC/MS system with on-line micro-furnace was used to make rapid evaluation of ω-chloroacetophenone (CN) decomposition under inert thermal atmospheres. The volatile products evolved during pyrolysis were analyzed by thermal gravimetric analysis (TGA) and Py-GC/MS to obtain specific thermogram and pyrogram.
Wladimir Solodenko et al.
Molecular diversity, 9(4), 333-339 (2005-11-29)
The preparation of a new palladium(II) complex with a 2-pyridinealdoxime ligand and its use as a Pd(0) precatalyst in the cross-coupling Suzuki-Miyaura reaction is described. Several concepts for the immobilization of this catalytic system are presented and compared in order
Expanding the [1,2]-aryl migration to the synthesis of substituted indoles.
Tao Pei et al.
Angewandte Chemie (International ed. in English), 47(22), 4231-4233 (2008-04-30)
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