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Merck
CN

77870

(S)-(-)-α-甲基苄胺

purum, ≥98.0% (sum of enantiomers, GC)

别名:

(S)-(-)-1-苯乙胺

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关于此项目

线性分子式:
C6H5CH(CH3)NH2
化学文摘社编号:
分子量:
121.18
EC Number:
220-098-0
UNSPSC Code:
12352116
PubChem Substance ID:
Beilstein/REAXYS Number:
2204907
MDL number:
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vapor pressure

0.5 mmHg ( 20 °C)

grade

purum

assay

≥98.0% (sum of enantiomers, GC)

optical activity

[α]20/D −30±2°, c = 10% in ethanol

optical purity

enantiomeric ratio: ≥97:3 (GC)

refractive index

n20/D 1.526 (lit.), n20/D 1.528

bp

187 °C (lit.)

density

0.94 g/mL at 25 °C (lit.)

SMILES string

C[C@H](N)c1ccccc1

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m0/s1

InChI key

RQEUFEKYXDPUSK-ZETCQYMHSA-N

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pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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Alejandra León et al.
Journal of natural products, 75(5), 859-864 (2012-05-12)
The enantiomeric lactams (-)-8, (+)-8, (+)-9, and (-)-9 were formed by the reaction of the dimeric phthalide rac-tokinolide B (rac-3) with (R)-(+)-α-methylbenzylamine and (S)-(-)-α-methylbenzylamine. The absolute configurations of compounds 8 and 9 were assigned by experimental and theoretically calculated electronic
Barry Lygo et al.
Organic & biomolecular chemistry, 10(25), 4968-4976 (2012-05-23)
A short synthetic route to diastereoisomeric atropos dihydro-5H-dibenz[c,e]azepinium salts via reaction of a single enantiomer of (R)-α-methylbenzylamine with a racemic atropos biphenol derivative is described. Compounds prepared via this approach are used to provide strong evidence that structurally related tropos
Christian Merten et al.
Chirality, 22(8), 754-761 (2010-02-27)
Chiral alpha-methylbenzyl amine is a well known and often used chiral auxiliary, e.g., in the resolution of racemates or asymmetric catalysis. In this work, alpha-methylbenzyl amine and its derivatives N,alpha-dimethylbenzyl amine, N,N,alpha-trimethylbenzyl amine, and bis[alpha-methylbenzyl] amine were investigated by vibrational
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The journal of physical chemistry. B, 111(31), 9239-9243 (2007-07-20)
A polydomain cholesteric elastomer was obtained by cross-linking a nematic side-chain polysiloxane in the presence of a chiral dopant. After extraction of the chiral dopant, sorption experiments were performed, by the use of an electronic microbalance, in the presence of

全球贸易项目编号

货号GTIN
R7385-.5MG04061833274040
R7385-10MG04061833274057
R7385-1MG04061826676806
R7385-25MG04061833274064
R7385-5MG04061833274071

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