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Merck
CN

79840

N-邻苯二甲酰-L-谷氨酸

purum, ≥98.0% (T)

别名:

PhGA

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关于此项目

经验公式(希尔记法):
C13H11NO6
化学文摘社编号:
分子量:
277.23
PubChem Substance ID:
UNSPSC Code:
12352200
Beilstein/REAXYS Number:
90136
MDL number:
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grade

purum

assay

≥98.0% (T)

optical activity

[α]20/D −48±2°, c = 3% in dioxane

mp

160-162 °C

application(s)

peptide synthesis

SMILES string

OC(=O)CC[C@H](N1C(=O)c2ccccc2C1=O)C(O)=O

InChI

1S/C13H11NO6/c15-10(16)6-5-9(13(19)20)14-11(17)7-3-1-2-4-8(7)12(14)18/h1-4,9H,5-6H2,(H,15,16)(H,19,20)/t9-/m0/s1

InChI key

FEFFSKLJNYRHQN-VIFPVBQESA-N

Other Notes

L-谷氨酸的 N-保护衍生物。其酸酐(无外消旋下通过 DCCI 或 Ac2O 制备)被用于 γ-L-谷氨酰基化;邻苯二甲酰基保护基可在温和条件下除去


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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分析证书(COA)

Lot/Batch Number

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P Lindberg et al.
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A Szent-Gyorgyi et al.
The Journal of organic chemistry, 41(9), 1603-1606 (1976-04-30)
-Glutamyl cyclotransferase. Distribution, isozymic forms, and specificity.
M Orlowski et al.
The Journal of biological chemistry, 248(8), 2836-2844 (1973-04-25)