产品名称
三氯乙酰氯, for GC derivatization, derivatization grade (GC derivatization), ≥98.5%
InChI
1S/C2Cl4O/c3-1(7)2(4,5)6
InChI key
PVFOMCVHYWHZJE-UHFFFAOYSA-N
SMILES string
ClC(=O)C(Cl)(Cl)Cl
grade
derivatization grade (GC derivatization)
vapor pressure
16 mmHg ( 20 °C)
assay
≥98.5%
98.5-101.5% (AT)
form
liquid
reaction suitability
reagent type: derivatization reagent
reaction type: Acylations
refractive index
n20/D 1.470 (lit.)
n20/D 1.470-1.472
bp
114-116 °C (lit.)
mp
−57 °C (lit.)
density
1.629 g/mL at 25 °C (lit.)
Quality Level
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
213.8 °F - open cup
flash_point_c
101 °C - open cup
法规信息
新产品
此项目有
Hülya Senöz et al.
Chemical & pharmaceutical bulletin, 51(4), 444-447 (2003-04-04)
The pyrrolidine and morpholine enamines of cyclic ketones such as cyclohexanone and cyclopentanone were successfully diacetylated at alpha- and alpha'-positions with trichloroacetyl chloride using zinc catalyst. Morpholine enamines of the cyclic ketones gave acetylated morpholine in good yields besides the
A M Saillenfait et al.
Archives of toxicology, 70(2), 71-82 (1995-01-01)
The embryotoxicity of trichloroethylene (TRI), tetrachloroethylene (PER), and of four of their oxidative metabolites i.e. trichloroacetic acid, dichloroacetic acid, chloral hydrate, and trichloroacetyl chloride, was studied in vitro, using the rat whole embryo culture system. Embryos from Sprague-Dawley rats were
Taigo Kashiwabara et al.
The Journal of organic chemistry, 74(24), 9433-9439 (2009-11-20)
Chlorinative dimerization of terminal alkynes with trichloroacetyl chloride as chlorine donor proceeds in the presence of rhodium catalysts to give (Z,Z)-1,4-dichloro-1,3-butadienes stereoselectively. Ligand screening has revealed that reactions using sterically bulky and electron-donating ligands like trimesitylphosphine are high yielding. The
D Reichert et al.
Mutation research, 117(1-2), 21-29 (1983-04-01)
Dichloroacetylene (DCA) is a highly reactive compound that decomposes rapidly in contact with air into a series of chlorinated aliphatic hydrocarbons (e.g., phosgene, trichloroacetyl chloride, trichloroacryloyl chloride and hexachlorobutadiene). Experiments were performed to compare the mutagenic properties of DCA and
E Eliasson et al.
Chemico-biological interactions, 116(1-2), 123-141 (1999-01-07)
Halothane hepatitis occurs because susceptible patients mount immune responses to trifluoroacetylated protein antigens, formed following cytochrome P450-mediated bioactivation of halothane to trifluoroacetyl chloride. In the present study, an in vitro approach has been used to investigate the cytochrome P450 isozyme(s)
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