80521
三氯乙酰氯
for GC derivatization, derivatization grade (GC derivatization), ≥98.5%
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关于此项目
线性分子式:
Cl3CCOCl
化学文摘社编号:
分子量:
181.83
Beilstein:
774120
EC 号:
MDL编号:
UNSPSC代码:
12352200
PubChem化学物质编号:
NACRES:
NA.22
等级
derivatization grade (GC derivatization)
质量水平
蒸汽压
16 mmHg ( 20 °C)
方案
≥98.5%
98.5-101.5% (AT)
表单
liquid
反应适用性
reagent type: derivatization reagent
reaction type: Acylations
折射率
n20/D 1.470 (lit.)
n20/D 1.470-1.472
沸点
114-116 °C (lit.)
mp
−57 °C (lit.)
密度
1.629 g/mL at 25 °C (lit.)
SMILES字符串
ClC(=O)C(Cl)(Cl)Cl
InChI
1S/C2Cl4O/c3-1(7)2(4,5)6
InChI key
PVFOMCVHYWHZJE-UHFFFAOYSA-N
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警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
213.8 °F - open cup
闪点(°C)
101 °C - open cup
法规信息
新产品
此项目有
B Roig et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(13), 2925-2930 (2002-12-13)
Within the framework of the monitoring of the trichloroacetylchloride (TCAC) photosynthesis, ultra-violet (UV) spectrophotometry is proposed as a simple and rapid tool allowing, in real time, the control of the process efficiency. A good correlation has been obtained between the
A M Saillenfait et al.
Archives of toxicology, 70(2), 71-82 (1995-01-01)
The embryotoxicity of trichloroethylene (TRI), tetrachloroethylene (PER), and of four of their oxidative metabolites i.e. trichloroacetic acid, dichloroacetic acid, chloral hydrate, and trichloroacetyl chloride, was studied in vitro, using the rat whole embryo culture system. Embryos from Sprague-Dawley rats were
Hülya Senöz et al.
Chemical & pharmaceutical bulletin, 51(4), 444-447 (2003-04-04)
The pyrrolidine and morpholine enamines of cyclic ketones such as cyclohexanone and cyclopentanone were successfully diacetylated at alpha- and alpha'-positions with trichloroacetyl chloride using zinc catalyst. Morpholine enamines of the cyclic ketones gave acetylated morpholine in good yields besides the
E Eliasson et al.
Chemico-biological interactions, 116(1-2), 123-141 (1999-01-07)
Halothane hepatitis occurs because susceptible patients mount immune responses to trifluoroacetylated protein antigens, formed following cytochrome P450-mediated bioactivation of halothane to trifluoroacetyl chloride. In the present study, an in vitro approach has been used to investigate the cytochrome P450 isozyme(s)
Taigo Kashiwabara et al.
The Journal of organic chemistry, 74(24), 9433-9439 (2009-11-20)
Chlorinative dimerization of terminal alkynes with trichloroacetyl chloride as chlorine donor proceeds in the presence of rhodium catalysts to give (Z,Z)-1,4-dichloro-1,3-butadienes stereoselectively. Ligand screening has revealed that reactions using sterically bulky and electron-donating ligands like trimesitylphosphine are high yielding. The
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