80521
三氯乙酰氯
for GC derivatization, derivatization grade (GC derivatization), ≥98.5%
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关于此项目
线性分子式:
Cl3CCOCl
化学文摘社编号:
分子量:
181.83
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-926-7
Beilstein/REAXYS Number:
774120
MDL number:
Assay:
≥98.5%, 98.5-101.5% (AT)
Form:
liquid
InChI
1S/C2Cl4O/c3-1(7)2(4,5)6
InChI key
PVFOMCVHYWHZJE-UHFFFAOYSA-N
SMILES string
ClC(=O)C(Cl)(Cl)Cl
grade
derivatization grade (GC derivatization)
vapor pressure
16 mmHg ( 20 °C)
assay
≥98.5%, 98.5-101.5% (AT)
form
liquid
reaction suitability
reagent type: derivatization reagent
reaction type: Acylations
Quality Level
refractive index
n20/D 1.470-1.472
bp
114-116 °C (lit.)
mp
−57 °C (lit.)
density
1.629 g/mL at 25 °C (lit.)
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
213.8 °F - open cup
flash_point_c
101 °C - open cup
法规信息
新产品
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A M Saillenfait et al.
Archives of toxicology, 70(2), 71-82 (1995-01-01)
The embryotoxicity of trichloroethylene (TRI), tetrachloroethylene (PER), and of four of their oxidative metabolites i.e. trichloroacetic acid, dichloroacetic acid, chloral hydrate, and trichloroacetyl chloride, was studied in vitro, using the rat whole embryo culture system. Embryos from Sprague-Dawley rats were
Hülya Senöz et al.
Chemical & pharmaceutical bulletin, 51(4), 444-447 (2003-04-04)
The pyrrolidine and morpholine enamines of cyclic ketones such as cyclohexanone and cyclopentanone were successfully diacetylated at alpha- and alpha'-positions with trichloroacetyl chloride using zinc catalyst. Morpholine enamines of the cyclic ketones gave acetylated morpholine in good yields besides the
B Roig et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(13), 2925-2930 (2002-12-13)
Within the framework of the monitoring of the trichloroacetylchloride (TCAC) photosynthesis, ultra-violet (UV) spectrophotometry is proposed as a simple and rapid tool allowing, in real time, the control of the process efficiency. A good correlation has been obtained between the
E Eliasson et al.
Chemico-biological interactions, 116(1-2), 123-141 (1999-01-07)
Halothane hepatitis occurs because susceptible patients mount immune responses to trifluoroacetylated protein antigens, formed following cytochrome P450-mediated bioactivation of halothane to trifluoroacetyl chloride. In the present study, an in vitro approach has been used to investigate the cytochrome P450 isozyme(s)
D Reichert et al.
Mutation research, 117(1-2), 21-29 (1983-04-01)
Dichloroacetylene (DCA) is a highly reactive compound that decomposes rapidly in contact with air into a series of chlorinated aliphatic hydrocarbons (e.g., phosgene, trichloroacetyl chloride, trichloroacryloyl chloride and hexachlorobutadiene). Experiments were performed to compare the mutagenic properties of DCA and
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